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等离子喷涂Al2O3与ZrO2复合热障涂层的高温性能
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TG154.5

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国防科技重点实验室基金项目资助(99JS.50.4.1)


Thermal Behavior of Thermal Barrier Coatings Composed with Al2O3 and ZrO2 Sprayed by Plasma
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    摘要:

    采用等离子喷涂(PS)方法,在GH536高温合金基材上制备了传统的双层热障涂层(TBCs)和2种含有Al2O3与ZrO2陶瓷复合层的3层热障涂层。传统TBC8结构为Ni22Cr10AlY合金连接层和8%Y2O3部分稳定的ZrO2(8YPSZ)陶瓷顶层;3层TBCs中分别采用置于8YPSZ陶瓷层内层及外层的Al2O3与8YPSZ复合层。3种类型试样的100h。1050℃静态氧化试验及1050℃热震试验结果表明:3层涂层较双层涂层的氧化阻力提高,双层涂层的热震阻力最佳,氧化阻力最差。不同复合层形式试样的热振失效方式和寿命也有差别,复合层置于陶瓷层外层热震寿命略高,但100h氧化增重有明显提高,抗氧化性降低。

    Abstract:

    Three types of thermal barrier coatin gs (TBCs )were prepared by plasma spray(PS)on GH536superalloy substrate with d ifferent layers.One is the traditional TBC wi th Ni22Cr10AlY as bond co at and ZrO 2-8wt%Y 2 O 3 (8YSZ)as top coat,the other two TBCs have a t riplex structure with comp osite layers of 8YSZ +Al 2 O 3 and ZrO 2 ,respectively.The static oxidatio n test and thermal shock tests were cond ucted to evaluate the oxidation kinetics and thermal shock cyclic lifetime of th e TBCs.With the different failure criterions,the failure mechanism of TBCs was discussed.The thermal shoc k resistance of state-of-the-art duplex TBCs is the best.It is indicated that the higher oxidation resis-tance is obtained by using of composite 8YSZ +Al 2 O 3 ceramic layer.It has the better oxid ation resistance if using 8YSZ +Al 2 O 3 as the inner composite layer of TBCs,comparing with as the out layer.

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张罡 武颖娜 梁勇 冯钟潮 巴瑞章.等离子喷涂Al2O3与ZrO2复合热障涂层的高温性能[J].稀有金属材料与工程,2003,(9):756~760.[Zhang Gang, Wu Yingna, Liang Yong, Feng Zhongchao, Ba Ruizhang . Thermal Behavior of Thermal Barrier Coatings Composed with Al2O3 and ZrO2 Sprayed by Plasma[J]. Rare Metal Materials and Engineering,2003,(9):756~760.]
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  • 最后修改日期:2001-09-29
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