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Influence of Pt on Oxidation Behavior of CoNiCrAlY Alloy

Influence of Pt on Oxidation Behavior of CoNiCrAlY Alloy
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National Natural Science Foundations of China (51071089)

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    摘要:

    利用扫描电镜、维氏硬度计、X射线衍射和能谱分析研究了CoNiCrAlY合金及添加3%、5%Pt (质量分数)改进的CoNiCrAlY合金组织、硬度及恒温氧化行为。结果表明:Pt在合金中形成了一种β-(Ni, Pt)Al相,显著改变了合金的组织;Pt的添加使得合金的硬度有了略微的提高;Pt促进了亚稳态的θ-Al2O3向稳态α-Al2O3的相转变,降低合金的氧化速率,Pt还抑制了β-相的消耗及内氧化的产生,提高了合金的抗氧化性能。

    Abstract:

    The microstructure, hardness and isothermal oxidation behavior of CoNiCrAlY alloy modified by addition of 3 wt% and 5 wt% Pt were investigated using scanning electron microscopy, Vickers hardness tester, X-ray diffraction and energy dispersive spectroscopy analysis. The results reveal that Pt has a significant influence on the microstructure of the experimental alloy by formation of β-(Ni,Pt)Al phase. Addition of Pt can slightly increase the hardness of the experimental alloys. Pt will accelerate the phase transformation of alumina from metastable θ-Al2O3 to stable α-Al2O3, which is the main reason for the lowering oxidation rate and the formation of a protective oxide scale on the Pt-containing alloys. Furthermore, adding of Pt can improve the Al transport, which suppresses the consumption of β-phase and eliminates the internal oxidation.

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兰 昊,杨志刚,张玉朵,张 弛. Influence of Pt on Oxidation Behavior of CoNiCrAlY Alloy[J].稀有金属材料与工程,2012,41(2):194~198.[Lan Hao, Yang Zhigang, Zhang Yuduo, Zhang Chi. Influence of Pt on Oxidation Behavior of CoNiCrAlY Alloy[J]. Rare Metal Materials and Engineering,2012,41(2):194~198.]
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  • 收稿日期:2011-03-25