+高级检索
Nb掺杂Gd合金的大磁热效应和显微硬度增强
DOI:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

基金项目:

广东省科技计划项目 (2010B050300008,2007B010600043);广东省教育部产学研结合项目 (2009B090300273);国家自然科学基金 (U0734001,50874050);中央高校基本科研业务费专项资金项目 (2009ZM0291,2009ZZ0025,2009ZM0247)


Large Magnetocaloric Effect and Improved Microhardness of Nb-doped Gd Alloys
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    在氩气气氛中用熔炼法制备了Gd100-xNbx (x=0, 1, 2, 3, 5)系列合金,铸锭经1273 K均匀化退火96 h后水淬至室温。结果表明:Gd100-xNbx 系列合金仍保持纯Gd的六方相结构;Nb掺杂合金的居里温度比纯Gd均低2 K,在居里点附近发生的磁性转变为二级相变,5 T外场下的最大磁熵变约为纯Gd的85%。通过少量Nb (≤5at%) 掺杂后,Gd100-xNbx系列合金的显微硬度明显得到提高,与纯Gd相比,显微硬度最大提高幅度达~53% (x=5)。含少量Nb的Gd100-xNbx合金具有较大的磁熵变和较好的加工性能,是一类有很大应用潜力的室温磁致冷材料

    Abstract:

    A series of Gd1- xNbx(x=0, 1, 2, 3, 5) alloys were prepared by arc melting in purified argon atmosphere. The ingots were heat-treated at 1273K for 96h followed by water quenching to homogenize the microstructure. All Gd1-xNbx alloys with various Nb doping keep the hexagonal crystal structure of pure Gd. The Curie temperatures Tc of the Nb-doped alloys are lower than that of Gd by ~2 K and the magnetic transition occurring in the vicinity of Tc is a second order transformation. The maximum entropy changes of Gd1-xNbx alloys under 5 T magnetic field are about 85% of that of pure Gd. The microhardness of Gd1- xNbx alloys is greatly improved by doping a small amount of Nb (≤5 at%). Comparing with pure Gd, the microhardness increases by about 53% for Gd1-xNbx alloys with x=5. The present results indicate that the Gd1- xNbx alloys with small amounts of Nb doping have large values of magnetic entropy change and good processing properties, they are possessed of great potential in room-temperature magnetic refrigeration applications

    参考文献
    相似文献
    引证文献
引用本文

唐鹏飞,钟喜春,郑志刚,余红雅,邱万奇,曾德长,刘仲武. Nb掺杂Gd合金的大磁热效应和显微硬度增强[J].稀有金属材料与工程,2012,41(6):1090~1093.[Tang Pengfei, Zhong Xichun, Zheng Zhigang, Yu Hongya, Qiu Wanqi, Zeng Dechang, Liu Zhongwu. Large Magnetocaloric Effect and Improved Microhardness of Nb-doped Gd Alloys[J]. Rare Metal Materials and Engineering,2012,41(6):1090~1093.]
DOI:[doi]

复制
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2011-06-20
  • 最后修改日期:
  • 录用日期:
  • 在线发布日期:
  • 出版日期: