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纳米SiO2颗粒增强NiTi基复合材料的制备及组织性能研究
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湖南省教育厅重点项目 (09A089);湘潭大学研究性创新课题项目 (091053003)


Preparation of Nano-SiO2 Particle Reinforced NiTi-Based Composites and Their Microstructure and Mechanical Properties
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    摘要:

    采用等离子烧结法 (SPS) 制备不同含量(1%~4%,质量分数)纳米SiO2增强NiTi基复合材料,研究SiO2添加对NiTi-SiO2复合材料的显微组织、相变点、力学性能及断裂特征的影响。结果表明,所制备的NiTi-SiO2复合材料其显微组织主要由B2-NiTi相、B19'-NiTi相、Ni3Ti相、Ti2Ni相以及SiO2相组成,SiO2颗粒均匀弥散地分布在NiTi基体中。随SiO2加入量的增加,合金的相变特征温度,Mf、As和Af 下降,但SiO2的添加量对Ms温度影响不大。SiO2颗粒对NiTi合金的强化效果明显,随颗粒加入量增加,其断裂方式由韧性断裂转变为脆性断裂。在6%变形范围内,添加SiO2颗粒的复合材料具有更高的回复率,表现出更好的超弹性

    Abstract:

    The nano-SiO2 particle reinforced NiTi matrix composites (SiO2%=1%~4%, mass fraction) were fabricated by Spark Plasma Sintering (SPS) method, and the effects of the contents of SiO2 nano-particles on the microstructure, the phase transformation points, the mechanical properties and the fracture feature were investigated. The results indicate that the microstructures of the composites mainly consist of the phases of B2-NiTi, B19'-NiTi, Ni3Ti, Ti2Ni and SiO2, and the SiO2 particles are evenly dispersed in NiTi matrix. The addition of SiO2 reduces the phase transformation point of Mf, As and Af, but has no strong influence on Ms. The SiO2 particles can obviously improve the strength of NiTi alloy, but with the increase of SiO2 particles, the fracture mode of the alloy changes from ductile fracture to brittle fracture. More over, the composites containing SiO2 exhibit higher deformation recovery and better superelasticity than that of NiTi alloy in the deformation within 6%

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李传吉,林建国,张德闯,彭柱根,吴昌义.纳米SiO2颗粒增强NiTi基复合材料的制备及组织性能研究[J].稀有金属材料与工程,2012,41(8):1385~1389.[Li Chuanji, Lin Jianguo, Zhang Dechuang, Peng Zhugen, Wu Changyi. Preparation of Nano-SiO2 Particle Reinforced NiTi-Based Composites and Their Microstructure and Mechanical Properties[J]. Rare Metal Materials and Engineering,2012,41(8):1385~1389.]
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  • 收稿日期:2011-08-06
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