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高场磁体用RRP Nb3Sn股线的研制
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国际合作项目(2010DFB50280);“863”计划(2007AA03Z205, 2009AA035401);国家“973”专项(2008CB717903);中国科技部 ITER专项(2008GB101001)


Fabrication and Investigation of Nb3Sn Strands by RRP for High Field Magnet
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    摘要:

    采用Rod Restack Process (RRP) 研制了单根线长大于1500 m的高场磁体用Nb3Sn股线,股线选用Nb作为扩散阻隔层,分布于各亚组元周围。在热处理时Nb阻隔层不但可以阻止Sn向稳定体Cu区的扩散,防止稳定体的Sn扩散污染,确保股线具有较高的剩余电阻率 (RRR),同时,靠近Sn源内侧的Nb参与固态扩散反应生成A15相Nb3Sn,贡献临界电流。在股线的制备过程中,采用Nb-47%Ti (质量分数) 芯代替部分Nb芯的方式添加元素Ti,达到了Ti元素添加目的,该方法因为使用了已经商业化的Nb-47%Ti而有效控制了制作成本。对该股线进行热处理以及超导性能测试研究表明:640 ℃, 60 h 热处理条件下,股线在12 T,4.2 K, 0.1 μV/cm下的Ic为514 A,股线的RRR为148,具有良好的绝热稳定性;在650 ℃, 100 h下股线的Ic为599 A,RRR=3.77。股线扩散阻隔层以及添Ti方式的成功选择,为获得长线打下了基础,为股线性能的初步研究及后续的实验提供了直接参考

    Abstract:

    The Nb3Sn strands over 1500 m piece length by Rod Restack Process (RRP) for high field magnet were fabricated by Western Superconducting Technologies Co., Ltd. (WST). The distributing Nb barriers were employed around each sub-element in the process, which not only protect the Cu stabilization from the pollution of Sn, but also contribute to the critical current for forming A15 phase Nb3Sn during the reaction. Meanwhile, Nb-47wt%Ti filaments were adopted to replace some of Nb as the resource of Ti adding in the process, lowering the production price the commercial Nb-47wt%Ti. The testing results show that the Ic of the strands with better stability is 514 A at 12 T, 4.2 K, 0.1 μV/cm with the heat treatment of 640 ℃, 60 h and the RRR value is 148. While the Ic is 599 A with the heat treatment of 665 ℃, 60 h and RRR value is 3.77. The success choosing of barrier and Ti doping make it possible to develop higher quality strands, including long piece length and high critical current

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李春广,孙霞光,邓胜涛,管军强,肖成举,万晓波,朱思华,李建峰,杜社军,王天成,张丰收,刘向宏,冯 勇.高场磁体用RRP Nb3Sn股线的研制[J].稀有金属材料与工程,2012,41(8):1413~1416.[Li Chunguang, Sun Xiaguang, Deng Shengtao, Guan Junqiang, Xiao Chengjun, Wan Xiaobo, Zhu Sihua, Li Jianfeng, Du Shejun, Wang Tiancheng, Zhang Fengshou, Liu Xianghong, Feng Yong. Fabrication and Investigation of Nb3Sn Strands by RRP for High Field Magnet[J]. Rare Metal Materials and Engineering,2012,41(8):1413~1416.]
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  • 收稿日期:2011-08-09
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