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热等静压原位生成Al2O3颗粒强化Ti4AlN3复合材料
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沈阳工业大学,沈阳工业大学,沈阳工业大学

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国家自然科学基金资助(51075199);江苏省普通高校研究生科研创新计划项目(CXZZ11_0341)


In situ synthesis of Ti4AlN3 reinforced with Al2O3 particles by hot isostatic pressing
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Shenyang University of Technology, Shenyang, 110870,,

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    摘要:

    利用Al3Ti/TiN纳米复合粉体在1280 ℃/150 MPa/1 h热等静压条件下,制备出Al2O3/Ti4AlN3复合材料。利用XRD、SEM和TEM研究复合材料的形貌及成分。研究表明复合材料主要由片层结构的Ti4AlN3基体和Al2O3颗粒增强相组成。Ti4AlN3基体的平均晶粒尺寸为7 μm;Al2O3颗粒的弥散分布,形状不规则,粒度在1-3 μm,体积分数约为27%。Al2O3/Ti4AlN3复合材料的强化机制为细晶强化和第二相粒子强化。Al2O3/Ti4AlN3复合材料与单相的Ti4AlN3材料相比,显微硬度从2.5 GPa提高到6.7 GPa,常温下最大压缩强度从450 MPa提高到1 800 MPa,最大压缩应变由4%提高到6.2%。

    Abstract:

    Bulk intermetallic-ceramic composite Al2O3/Ti4AlN3 was fabricated by in-situ hot isostatic pressing of Al3Ti/TiN nanopowders under 1280 ℃/150 MPa/1 h conditions . The microstructure of composite were investigated by X-ray diffraction, SEM(Scanning Electron Microscope) and TEM(Transmission Electron Microscope). It is revealed that matrix Ti4AlN3 grains are strip-like and Al2O3 particles disperse in matrix uniformly with irregular shape. The averagegrain size of Ti4AlN3 is 7 μm. The size of Al2O3 particles are in the range of 1-3 μm, and volume fraction is about 40%. The Vickers hardness of Al2O3/Ti4AlN3 composite is 6.7GPa, maximal compressed strength is 1 800 MPa. Maximum compressive strain increased from 4% to 6.2%.Compared with the micro-hardness and compressed strength,Al2O3/Ti4AlN3 composite is higher than single Ti4AlN3 phase. The strengthening mechanisms of composite are fine grain strengthening and second phase strengthening.

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郑卓,孙维民,刘正.热等静压原位生成Al2O3颗粒强化Ti4AlN3复合材料[J].稀有金属材料与工程,2016,45(7):1811~1815.[zhengzhuo, sunweimin, liuzheng. In situ synthesis of Ti4AlN3 reinforced with Al2O3 particles by hot isostatic pressing[J]. Rare Metal Materials and Engineering,2016,45(7):1811~1815.]
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  • 收稿日期:2013-06-21
  • 最后修改日期:2016-03-16
  • 录用日期:2016-03-29
  • 在线发布日期: 2016-10-09
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