+高级检索
Pt+Hf改性的γ-Ni+γ′-Ni3Al涂层结构及其抗氧化性能研究
DOI:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

基金项目:

上海市科学技术委员会 (10JC1405100,11520701200);国家自然科学基金 (51271107)


Investigation of Microstructures of Pt+Hf Modified γ-Ni+γ′-Ni3Al Coatings and Their Oxidation Resistance
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    通过包埋Al-Hf共渗在高温合金DZ417G表面制备出Pt+Hf 共同改性的γ-Ni+γ′-Ni3Al涂层。Al-Hf共渗过程中,Hf含量不同,涂层表面形成的相结构也不同。当渗剂中Hf含量为2%时(质量分数, 下同),涂层呈γ-Ni+γ′-Ni3Al结构;渗剂中Hf含量为6%时,涂层相结构为b-NiAl+Al16Hf6Ni7;而当Hf含量达到12%时,涂层相结构为Al16Hf6Ni7。随着后续热处理的进行,β-NiAl+Al16Hf6Ni7涂层的相结构转变为γ-Ni+γ′-Ni3Al;Al16Hf6Ni7涂层转变为γ-Ni+γ′-Ni3Al+Al3HfNi12结构。1100℃的等温氧化实验表明,经过10 h氧化,高温合金基体表面已经出现了脱落;而渗剂中Hf含量为2%时形成的Pt+Hf改性的γ-Ni+γ′-Ni3Al涂层经过30 h氧化后,其表面依然完整。与单纯的Pt改性的γ-Ni+γ′-Ni3Al涂层相比,Pt+Hf共同改性的γ-Ni+γ′-Ni3Al 涂层由于适量活性元素Hf的加入,其抗氧化性能得到了提高

    Abstract:

    The Pt and Hf modified γ-Ni+γ′-Ni3Al coatings were fabricated on the DZ417G superalloy substrates by combined aluminizing and hafnizing using a pack cementation. During the co-deposition process, the phase structure formed on the coating surface changes with the increasing of hafnium contents in packs. When the hafnium contents are 2 wt%, 6 wt% and 12 wt% the coatings consist of the γ-Ni+γ′-Ni3Al, b-NiAl+Al16Hf6Ni7, and Al16Hf6Ni7, respectively. During post heat treatment the β-NiAl+Al16Hf6Ni7 and Al16Hf6Ni7 coatings are transformed to γ-Ni+γ′-Ni3Al and γ-Ni+γ′-Ni3Al+Al3HfNi12. Isothermal oxidation tests at 1100 ℃ for 10 h show that there are a lot of spallation on the surface of the substrate without coating, while the Pt and Hf modified γ-Ni+γ′-Ni3Al coating formed in the packs with 2 wt% Hf remains to be integrated after being oxidized for 30 h. The addition of the reactive element hafnium makes a further improvement on the oxidation resistance of the Pt+γ-Ni+γ′-Ni3Al coatings

    参考文献
    相似文献
    引证文献
引用本文

姚培培,付 超,操光辉. Pt+Hf改性的γ-Ni+γ′-Ni3Al涂层结构及其抗氧化性能研究[J].稀有金属材料与工程,2014,43(1):224~228.[Yao Peipei, Fu Chao, Cao Guanghui. Investigation of Microstructures of Pt+Hf Modified γ-Ni+γ′-Ni3Al Coatings and Their Oxidation Resistance[J]. Rare Metal Materials and Engineering,2014,43(1):224~228.]
DOI:[doi]

复制
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2012-12-17
  • 最后修改日期:
  • 录用日期:
  • 在线发布日期: 2014-04-16
  • 出版日期: