In order to select a good cost-performance ratio?magnesium alloy as anode material, the electrochemical properties of AZ31B magnesium alloy under different processing conditions were investigated by electrochemical workstation, optical?microscope (OM), scanning electron microscopy (SEM) and energy dispersed spectroscopy (EDS). Extruded, rolled, cast-rolled and as-cast AZ31 magnesium alloys were prepared as the anode materials. The results show that under different processing conditions, the extruded alloy is the best cost-performance ratio anode material among the four alloys. It possesses?the most?negative equilibrium potential, the lowest?corrosion current?density and the smallest free corrosion rate indicating the highest electrochemical?activity due to the uniform fine grains and the second phase. Its corrosiun products are loose, dispersing uniformly on the extruded anode surface, prone to falling off which decrease the polarization?and increase the utilization of the anode. The electrochemical activity and the corrosion resistance of the rolled and the cast-rolled alloys are relatively low, compared with the extrude samples. Due to the coarse grains, as-cast defects and coarse second phase distributed along the grain boundaries, the as-cast alloy has unstable discharge curve and positive discharge potential. The corrosions of AZ31 magnesium alloy under different conditions are almost pitting corrosion.