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急冷Ag-Cu-Ge钎料薄带性能与钎焊界面特征
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昆明贵金属研究所

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Properties and Brazing Interface Characteristicsof Rapidly Solidified Ag-Cu-Ge Solder Ribbon
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Kunming Institute of Precious Metals

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    摘要:

    采用急法制备了Ag-Cu-Ge共晶钎料薄带。用DSC、XRD分析钎料合金的熔化温度及相组成。用扫描电子显微镜(SEM)观察钎料合金以及钎焊接头的组织形貌,并用能谱仪(EDS)进行成分分析。结果表明:急冷Ag-Cu-Ge钎料液相线降低了4.8℃,熔化区间减小了4.4℃;铸态钎料组织粗大,偏析严重,急冷态钎料组织显著细化,成分更加均匀;与同成分的普通钎料相比,急冷Ag-Cu-Ge钎料与铜和镍基体的润湿性和铺展性更好,过渡层的厚度更宽,钎焊接头剪切强度更高;钎料合金与铜母材形成层状固液同分化合物,而与镍母材形成了笋状固液异分化合物,这种嵌入式结构有利于提高钎焊接头的牢固性。

    Abstract:

    Ag-Cu-Ge eutectic solder ribbons were prepared by single roller rapid solidification. Melting temperature and phase composition of solder alloys were determined by DSC and XRD. The microstructure and morphology of solder alloys and brazing joints were observed by scanning electron microscope (SEM), and the chemical composition was analyzed by energy dispersive spectrometer (EDS). The results show that the liquidus temperature of rapidly solidified Ag-Cu-Ge solder decreases 4.8℃ and its melting temperature range reduces 4.4℃. The microstructure of cast solder is massive and heavy segregation, while rapidly solidified solder has finer microstructures and higher composition homogeneity; Rapidly solidified Ag-Cu-Ge solder has a better wettability and spreadability, wider transition layer thickness and higher shear strength of brazed joints with Cu and Ni substrate compared with the same constituent common solder. Congruent compounds which grows up as a layer is found on the interface of solder alloy with copper substrate, while incongruent compounds which grows up as bamboo shoot form is found on the interfaces of solder alloy and substrate. This embedded structure is helpful to improve the strength of brazed joints

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张利广.急冷Ag-Cu-Ge钎料薄带性能与钎焊界面特征[J].稀有金属材料与工程,2016,45(2):421~425.[zhangliguang. Properties and Brazing Interface Characteristicsof Rapidly Solidified Ag-Cu-Ge Solder Ribbon[J]. Rare Metal Materials and Engineering,2016,45(2):421~425.]
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  • 收稿日期:2014-03-14
  • 最后修改日期:2014-04-03
  • 录用日期:2014-04-15
  • 在线发布日期: 2016-07-19
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