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ZrC含量对钨材料组织和性能的影响
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中南大学粉末冶金研究院,中南大学粉末冶金研究院

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中图分类号:

TG146.4 11;TF124.5 2

基金项目:

国家教育部博士点基金;国家重点基础研究发展计划(973计划)


Effect of ZrC content on Microstructure and properties of tungsten materials
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Affiliation:

Powder Metallurgy Research Institute, Central South University,Powder Metallurgy Research Institute, Central South University

Fund Project:

National Natural Science Foundation of China (21077041); Science Foundation of Jilin Province of China (201205067)

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    摘要:

    采用“溶胶-非均相沉淀-喷雾干燥-热还原”制备了W-ZrC复合粉末,经氢气保护气氛高温烧结后制备出W-ZrC材料,研究了ZrC含量对W的力学性能和显微组织的影响。结果表明,W-ZrC材料的相对密度较纯W材料得到很大提高,其室温拉伸强度由粉末烧结态纯W的290MPa可提高至543MPa,材料的应变由1.7%增大至3.5%;ZrC第二相粒子作为障碍能有效阻碍钨晶界的移动,由纯W晶粒的100μm左右细化至10-15μm;纯W的断口形貌主要为沿晶解理断裂,添加ZrC第二相粒子后断口组织中出现了穿晶解理断裂,说明ZrC能够有效强化W的晶界强度,并起到良好的细晶强化和弥散强化作用。

    Abstract:

    W-ZrC composite powders were prepared by sol-heterogeneous precipitation-spray drying thermal reduction technology. W-ZrC material was prepared by high temperature sintering under hydrogen atmosphere. Effect of ZrC content on the microstructure and properties were investigated. The results show that the relative density of W-ZrC material is greatly improved compared with that of pure W, the room temperature tensile strength of W-ZrC material is twofold of pure W , which is 290MPa. And the strain of the material is increased from 1.7% to3.5%. The second phase particles of ZrC can effectively prevent the migration of grain boundary. The grain is refined from 100μm to 10-15μm. The fracture morphology of pure W is mainly intergranular fracture, but W-ZrC materials is visible in transgranular brittle fracture. ZrC can effectively enhance the strength of the grain boundary of W, and has good effect in fine grain strengthening and dispersion strengthening.

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李鹏飞,范景莲. ZrC含量对钨材料组织和性能的影响[J].稀有金属材料与工程,2016,45(11):2970~2974.[lipengfei, fanjinglian. Effect of ZrC content on Microstructure and properties of tungsten materials[J]. Rare Metal Materials and Engineering,2016,45(11):2970~2974.]
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  • 收稿日期:2014-08-13
  • 最后修改日期:2014-11-20
  • 录用日期:2014-12-25
  • 在线发布日期: 2016-12-08
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