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合金成分对Cu-Ni合金薄带再结晶织构形成的影响
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上海大学材料科学与工程学院,上海大学材料科学与工程学院

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TG166/TM26

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上海市“科技创新行动计划”重大科技项目(11DZ1100303)


Effect of alloying elements on the formation of recrystallization texture of Cu-Ni alloy tapes
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School of Materials Science and Engineering, Shanghai University,School of Materials Science and Engineering, Shanghai University

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    摘要:

    采用冷坩埚悬浮熔炼技术冶炼了Cu-18at.%Ni、Cu-32at.%Ni、Cu-52at.%Ni和Cu-72at.%Ni四种合金铸锭,铸锭经锻造、热轧、冷轧和再结晶退火,最终获得了厚度为80 μm的薄带。采用背散射电子衍射(EBSD)技术表征了合金再结晶织构,利用高分辨透射电镜(HRTEM)分析了显微组织结构。结果表明,四种Cu-Ni合金冷轧后的形变织构相似,但随着合金薄带中Ni含量增加,再结晶退火后立方织构的份额减少,晶粒取向变得散乱,晶粒尺寸明显变大;合金成分处于52-72at.%Ni范围时,形变合金在回复阶段的调幅分解是引起再结晶织构散乱的主要原因,Cu-Ni 合金的单相固溶体是形变-再结晶后获得立方织构的关键因素。

    Abstract:

    Cu-xat.%Ni (x = 18,32,52,72) alloy were smelted by cold crucible induction levitation melting, and tapes with a final thickness of 80μm were obtained after forging, hot rolling, cold rolling and recrystallization annealing. The recrystallization texture and microstructure of alloy tapes were characterized by electron backscatter diffraction technology (EBSD) and high resolution transmission electron microscopy (HRTEM) respectively. The results showed that the deformation texture of these Cu-Ni alloys are similar, but with the increase of Ni content, the volume fraction of cube texture in alloy tapes decreased after recrystallization annealing, the grain orientation became scattered, and grain size significantly became larger. In the alloys with a composition of 52-72at.%Ni, spinodal decomposition occurred at recovery stage is the main cause of scattered recrystallization texture; single-phase solid solution of Cu-Ni alloy is the key element in obtaining cube texture after recrystallization.

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贺英,王均安.合金成分对Cu-Ni合金薄带再结晶织构形成的影响[J].稀有金属材料与工程,2016,45(11):2975~2980.[He Ying, Wang Jun-an. Effect of alloying elements on the formation of recrystallization texture of Cu-Ni alloy tapes[J]. Rare Metal Materials and Engineering,2016,45(11):2975~2980.]
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  • 收稿日期:2014-08-28
  • 最后修改日期:2014-12-03
  • 录用日期:2014-12-25
  • 在线发布日期: 2016-12-08
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