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以石墨烯为碳源的硬质合金制备与性能研究
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北京工业大学,北京工业大学

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“863”计划主题项目(SS2013AA031401);国家自然科学基金(51174009);北京市自然科学基金重点项目(2131001)


A STUDY ON PREPARATION AND MECHANICAL PROPERTIES OF HARD METALS USING GRAPHENE AS CARBON SOURCE
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Beijing University of Technology,Beijing university of technology

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    摘要:

    以N-甲基吡咯烷酮分散的石墨烯代替常规的冶金炭黑作为碳源,采用短流程原位还原碳化反应制备出纳米晶WC-Co复合粉末,石墨烯作为碳源可显著降低原位还原碳化反应温度,复合粉末粒径细小且分布均匀。采用放电等离子烧结系统对复合粉末进行快速烧结致密化,得到平均晶粒尺寸为~290nm的超细晶硬质合金块体材料,具有硬度值HV30为1387.7±13.1kg/mm2,断裂韧性KIC值为8.3±0.1MPa?m1/2的良好力学性能,通过HRTEM观测得到试样中WC/WC晶界、WC/Co相界、WC/C相界具有很高的匹配度。

    Abstract:

    In the present work,normal carbon source black carbon was substituted by graphene which was dispersed in N-Methyl-2-pyrrolidone and was used to prepare nanocrystalline WC-Co composite powders using short process in-situ reduction and carbonization reaction method. The results show that graphene as carbon source could reduce reaction temperature, and the particles diameter of WC-Co composite powders distribute slightly. Composite powders were consolidated through spark plasma sintering system and the mean grain size of WC in WC-Co cemented carbides is about 290nm. Vickers hardness and fracture toughness of the bulk was 1387.7?3.1kg/mm2 and 8.3?.1MPa?m1/2. The interfaces between WC/WC, WC/Co and WC/C were studied through HRTEM images and had grain boundaries with low misfit.

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王西龙,宋晓艳.以石墨烯为碳源的硬质合金制备与性能研究[J].稀有金属材料与工程,2016,45(12):3262~3266.[wangxilong, Song Xiaoyan. A STUDY ON PREPARATION AND MECHANICAL PROPERTIES OF HARD METALS USING GRAPHENE AS CARBON SOURCE[J]. Rare Metal Materials and Engineering,2016,45(12):3262~3266.]
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历史
  • 收稿日期:2014-09-28
  • 最后修改日期:2015-02-03
  • 录用日期:2015-03-25
  • 在线发布日期: 2017-02-06
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