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超高温热处理对不同工艺制备的W/ZrC金属陶瓷微观组织结构的影响
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国防科学技术大学,国防科技大学新型陶瓷纤维及其复合材料重点实验室,国防科技大学新型陶瓷纤维及其复合材料重点实验室,国防科技大学新型陶瓷纤维及其复合材料重点实验室

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TG146.411,TB331

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上海航天科技创新基金项目;湖南省高校科技创新团队支持计划资助;国防科技大学创新群体资助


Effect of ultra-high temperature heat treatment on microstructures of W/ZrC cermets fabricated by different routes
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National University of Defense Technology,Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, National University of Defense Technology,Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, National University of Defense Technology,Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, National University of Defense Technology

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    摘要:

    分别采用置换填充工艺(DCP)和热压烧结工艺(HP)制备了W/ZrC金属陶瓷,然后在2600℃下对其进行热处理1h,研究了热处理前后两种W/ZrC金属陶瓷的组织结构变化。研究表明热处理后两种材料都出现开孔率增大、线膨胀及质量损失。其中DCP法W/ZrC金属陶瓷在热处理后仍由分散分布的W颗粒相和连续的ZrC相组成,但原始材料中残留的WC、W2C及Zr-Cu合金相都消失,取而代之的是大量的空隙,同时W相含量也急剧减小。而HP法W/ZrC金属陶瓷在热处理后则有新相W2C生成,同时其W颗粒相有聚集的趋势,形成了大块团状相。

    Abstract:

    W/ZrC cermets were fabricated by Displacive Compensation of Porosity (DCP) and Hot Pressing (HP), and then they were heat treated at 2600°C for 1 h. Microstructure changes of W/ZrC cermets before and after heat treatment were investigated. Results showed that both of two W/ZrC cermets had an increase of open porosity, a linear expansion and a weight loss after the heat treatment. Annealed DCP-derived W/ZrC cermets were still composed of dispersive W phases and continuous ZrC phases, but residual WC, W2C and Zr-Cu alloy were gone, instead, a large increase of pores and a sharp reduction of W phases appearing. While a new phase of W2C was formed in annealed HP-derived W/ZrC cermets, and W grains had a tendency to congregate together to form a big agglomerate phase.

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余艺平,王松,李伟,蒋进明.超高温热处理对不同工艺制备的W/ZrC金属陶瓷微观组织结构的影响[J].稀有金属材料与工程,2017,46(1):63~67.[yuyiping, Wang Song, Li Wei, Jiang Jin Ming. Effect of ultra-high temperature heat treatment on microstructures of W/ZrC cermets fabricated by different routes[J]. Rare Metal Materials and Engineering,2017,46(1):63~67.]
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  • 收稿日期:2014-10-13
  • 最后修改日期:2014-11-06
  • 录用日期:2014-12-25
  • 在线发布日期: 2017-03-16
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