+高级检索
Fe-C-Ta三元系相关系的实验测定与热力学计算
DOI:
作者:
作者单位:

湘潭大学 材料科学与工程学院;湘潭大学 材料设计及制备技术湖南省重点实验室,湘潭大学 材料科学与工程学院;湘潭大学 材料设计及制备技术湖南省重点实验室,湘潭大学 材料科学与工程学院;湘潭大学 材料设计及制备技术湖南省重点实验室,湘潭大学 材料科学与工程学院;湘潭大学 材料设计及制备技术湖南省重点实验室

作者简介:

通讯作者:

中图分类号:

TG113.12

基金项目:

国家自然科学基金项目(面上项目)


Experimental investigation and Thermodynamic calculation of the Fe-C-Ta system
Author:
Affiliation:

School of Materials Science and Engineering, Xiangtan University;Key Laboratory of Materials Design and Preparation Technology of Hunan Province, Xiangtan University,School of Materials Science and Engineering, Xiangtan University;Key Laboratory of Materials Design and Preparation Technology of Hunan Province, Xiangtan University,School of Materials Science and Engineering, Xiangtan University;Key Laboratory of Materials Design and Preparation Technology of Hunan Province, Xiangtan University,School of Materials Science and Engineering, Xiangtan University;Key Laboratory of Materials Design and Preparation Technology of Hunan Province, Xiangtan University

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    采用差热分析(DTA)测定了Fe-C-Ta三元系中Fe-xC-0.1Ta和Fe-xC-0.5Ta两个垂直截面,并选取Fe-2.93C-0.1Ta和Fe-2.31C-0.5Ta两种合金,对其相变过程进行了分析。利用CALPHAD方法,并结合实验数据对该体系的相关系进行了热力学优化。结果表明,计算结果与实验结果符合较好。该体系富铁角的液相面投影存在四个四相恒温反应:Liquid bcc ? fcc TaC,Liquid ? bcc Fe2Ta TaC,Liquid ? Fe3C TaC fcc,Liquid Ta2C? TaC Fe2Ta,反应温度分别为1443.26℃、1413.90℃、1122.42℃及1508.64℃。Fe-xC-0.1Ta合金和Fe-xC-0.5Ta合金在726.6℃发生共析反应。

    Abstract:

    Two vertical sections of the Fe-C-Ta system with 0.1wt.%,0.5wt.% ta were experimentally investigated by DTA, and the phase transformation sequences of the alloys Fe-2.93C-0.1Ta and Fe-2.31C-0.5Ta were analyzed. A thermodynamic calculation of this system was carried out using CALPHAD technique. The results show that the thermodynamically calculated results agree well with the experimental data. There are four nonvariant reactions in the liquidus projection of Fe-C-Ta system in the Fe-rich corner: Liquid bcc ?fcc TaC,Liquid ? bcc Fe2Ta TaC,Liquid ? Fe3C TaC fcc,Liquid Ta2C ? TaC Fe2Ta. The temperature of the nonvariant reactions is as following: 1443.26℃, 1413.90 ℃,1122.42 ℃, 1508.64℃.The eutectoid reaction occurred at 726.6℃of the alloys Fe-2.93C-0.1Ta and Fe-2.31C-0.5Ta.

    参考文献
    相似文献
    引证文献
引用本文

徐展源,欧阳雪枚,尹付成,李智. Fe-C-Ta三元系相关系的实验测定与热力学计算[J].稀有金属材料与工程,2017,46(1):97~103.[Xu Zhanyuan, OuYang Xuemei, Yin Fucheng, Li Zhi. Experimental investigation and Thermodynamic calculation of the Fe-C-Ta system[J]. Rare Metal Materials and Engineering,2017,46(1):97~103.]
DOI:[doi]

复制
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2014-10-16
  • 最后修改日期:2015-04-16
  • 录用日期:2015-06-11
  • 在线发布日期: 2017-03-16
  • 出版日期: