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等离子喷涂YSZ热障涂层桩钉结构激光表面改性
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华南理工大学,广州有色金属研究院

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The peg-nail structure selective laser modification of plasma sprayed YSZ thermal barrier coatings
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South China University of Technology,Guangzhou Research Institute of Non-ferrous Metals

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    摘要:

    实验采用大气等离子喷涂技术在镍基高温合金基体表面制备了ZrO2-7%Y2O3 热障涂层,利用Nd:YAG脉冲激光对YSZ涂层进行桩钉结构选择性激光表面改性。重点考察桩钉结构激光表面改性对涂层的组织结构和性能的影响。结果显示,桩钉结构激光表面改性有助于降低涂层表面的粗糙度,消除表面的孔隙,产生了垂直于表面的网状裂纹。桩钉结构激光改性区域的横截面出现柱状晶及等轴晶结构。XRD分析表明,喷涂涂层和激光表面改性区都存在有非平衡T'' 四方相,但是经过激光表面改性后,喷涂涂层中的单斜相M消失,同时在2θ为72-76°范围内非平衡T'' 在[004]方向增强。拉伸结果显示,桩钉结构选择性激光表面改性涂层的结合强度由喷涂涂层的7.3MPa增加到13.3MPa。隔热测试结果表明,相对于喷涂涂层,桩钉结构激光表面改性涂层的隔热性能有所下降,这是由于激光表面改性造成陶瓷层结构改变所致。

    Abstract:

    In this paper, yttria partially stabilized zirconia (YSZ) thermal barrier coatings (TBCs) were deposited by air plasma spraying (APS) method on nickle-based superalloy with initially sprayed NiCoCrAlYTa bond coat. After that, the surface of the plasma sprayed TBCs was subjected to the peg-nail structure selective laser modification using a Nd:YAG pulsed laser. The microstructure and performance of the plasma sprayed and laser modified YSZ coatings were investigated. The results revealed that the peg-nail structure selective laser modification helped to reduce the surface roughness considerably, eliminate to surface porosities and produced a network of continuous cracks perpendicular to the surface. The microstructure of laser modified area consisted of columnar grains in the cross-section and equiaxed grains on the surface. XRD patterns showed that both as-sprayed and the peg-nail structure laser modified coatings consisted of nonequibrium tetragonal (T'') phase, however, monoclinic (M) phase disappeared and intensity of T'' phase slightly increased in the range of 72-76°(2θ) after the peg-nail structure laser modification. It has been found that the average bond strength YSZ coatings was enhanced from 7.3 MPa to 13.3 MPa after the peg-nail structure laser modification. Thermal insulation capability of the peg-nail structure laser modified TBCs, as compared to the as-sprayed TBCs, was decreased due to microstructure change in the ceramic top coat.

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常发,周克崧.等离子喷涂YSZ热障涂层桩钉结构激光表面改性[J].稀有金属材料与工程,2017,46(3):577~584.[changfa, zhou ke song. The peg-nail structure selective laser modification of plasma sprayed YSZ thermal barrier coatings[J]. Rare Metal Materials and Engineering,2017,46(3):577~584.]
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历史
  • 收稿日期:2014-11-18
  • 最后修改日期:2015-05-28
  • 录用日期:2015-07-10
  • 在线发布日期: 2017-05-18
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