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CNTs和Ti掺杂对W基合金微观组织结构 及力学性能的影响
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大连理工大学 航空航天学院,大连理工大学 航空航天学院,大连理工大学 航空航天学院,大连理工大学 航空航天学院,大连理工大学 航空航天学院

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TG146.4

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国家自然科学基金资助项目( 50871092);中央高校基本科研业务费专项基金资助项目(DUT11ZD(G)01)


Influence of CNTs and Ti on the microstructure and mechanical properties of W-based alloys
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School of Aeronautics and Astronautics, DUT,School of Aeronautics and Astronautics, DUT,School of Aeronautics and Astronautics, DUT,School of Aeronautics and Astronautics, DUT,School of Aeronautics and Astronautics, DUT

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    摘要:

    采用高能球磨与热压工艺,在1500℃、25 MPa 压力下制备了CNTs和Ti掺杂的W基合金。利用三点弯曲法和单边缺口梁法(SENB)分别对合金的弯曲强度和断裂韧性进行了测试。使用扫描电镜(SEM)和能谱(EDS)分析仪对合金的微观组织形貌进行了观察与分析。结果表明:单独掺杂 CNTs和Ti都可以改善W合金的烧结性能,制备的W-0.1CNTs和W-5Ti合金的致密度显著提高,但晶粒尺寸较大。而同时掺杂 CNTs和Ti不仅可以改善W合金的烧结性能,而且可以明显抑制W晶粒长大;CNTs含量对W合金力学性能有明显的影响,对于W-5Ti-0.1CNTs合金,力学性能最好,其硬度、弯曲强度和断裂韧性分别为7.32GPa、654.3MPa、10.13MPa?m1/2;断口微观组织形貌分析表明,单纯加入CNTs或Ti,断裂方式是以沿晶断裂为主,Ti的加入,在W晶粒的三重粒界处形成Ti(W)固溶体;而同时加入CNTs和Ti所制备的W合金,晶粒大大细化,断裂方式由沿晶断裂转变为沿晶断裂和穿晶解理断裂的混合模式,CNTs和Ti的同时加入对W基材料起到了很好的增强增韧效果。

    Abstract:

    W-based alloys were fabricated at 1500℃ under a pressure of 25 MPa by high-energy ball milling and hot pressing,where the CNTs and Ti were used as the dopants.The influence of different dopants on the sintering density,morphologies and mechanical properties of sintered W-based materials was investigated. The microstructure was characterized by scanning electron microscopy (SEM) with energy dispersive spectrometer (EDS). The fracture strength and toughness were measured by three-point bending and single-edge notched beams tests, respectively. Density measurements indicated that both CNTs and Ti can effectively enhance the sintering behavior. The W-0.1CNTs and W-5Ti exhibited a high relative density of 95.8% and 96.5%, but their grain size is large. In case of W-5Ti-0.1CNTs alloy, the density is high and the addition of CNTs and Ti can refrain the grain size. W-5Ti-0.1CNTs alloy showed the excellent mechanical properties. The microhardness, fracture strength and fracture toughness of W-5Ti-0.1CNTs alloy are 7.32GPa, 654.3MPa, 10.13MPa?m1/2. The microstructure analysis of fracture surface revealed that the intergranular fracture is the main mode for the W-0.1CNTs and W-5Ti alloys, but the W-5Ti-0.1CNTs fractured in a mixture mode of intergranular and transgranular fracture. These results demonstrated that both the addition of CNTs and Ti can refine the microstructure and enhance the strength and fracture toughness of W-based alloys.

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张玉翠,沙建军,王永昌,王首豪,杨晓丽. CNTs和Ti掺杂对W基合金微观组织结构 及力学性能的影响[J].稀有金属材料与工程,2017,46(3):835~840.[Zhang Yucui, Sha Jianjun, Wang Yongchang, Wang Shouhao, Yang Xiaoli. Influence of CNTs and Ti on the microstructure and mechanical properties of W-based alloys[J]. Rare Metal Materials and Engineering,2017,46(3):835~840.]
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  • 收稿日期:2014-11-19
  • 最后修改日期:2015-03-31
  • 录用日期:2015-05-13
  • 在线发布日期: 2017-05-18
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