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Cu含量对Ti-Al-Si-Cu-N纳米薄膜结构及高温抗氧化性能的影响
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南昌航空大学材料科学与工程学院,南昌航空大学,南昌航空大学,江西科技师范大学,南昌航空大学,南昌航空大学

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TG174.444

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Effects of Cu content on microstructure and high-temperature oxidation behavior of Ti-Al-Si-Cu-N nanocomposite films
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Materials Science and Engineering, Nanchang Hangkong University,Nanchang Hangkong University,Nanchang Hangkong University,Jiangxi Science and Technology Normal University,Nanchang Hangkong University,Nanchang Hangkong University

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    摘要:

    本文通过磁控溅射技术,在AISI-304不锈钢表面制备了不同Cu含量的Ti-Al-Si-Cu-N纳米复合涂层。通过扫描电镜(SEM)、能谱仪(EDS)、X射线衍射(XRD)、纳米压痕仪和自制压痕仪等设备研究了Ti-Al-Si-N 和 Ti-Al-Si-Cu-N 纳米复合涂层的结构和在800℃氧化的行为。研究结果表明:随着涂层中Cu含量的增加,涂层表面的微孔数量减少,涂层更加致密,涂层晶粒尺寸减小,择优取向由(111)向(110)逐渐转变。涂层的硬度由14.76 GPa 增加至19.42 GPa。Cu含量为1.72 at%的Ti-Al-Si-Cu-N 弹性模量最小,为104.5 GPa。 Cu元素对Ti-Al-Si-Cu-N纳米复合涂层抗氧化性能有两方面:一是促进Al元素的扩散,二是在氧化膜表面形成裂纹和微孔缺陷。Ti-Al-Si-N 涂层比Ti-Al-Si-Cu-N涂层具有更好的抗氧化性能。

    Abstract:

    In this study, Ti-Al-Si-Cu-N nanocomposite films with different Cu contents were deposited on AISI-304 stainless steel by DC reactive magnetron sputtering. Both Ti-Al-Si-N and Ti-Al-Si-Cu-N nanocomposite films were oxidized at 800℃ to investigate the influence of Cu content on the microsturcture and high temperature oxidation resistance by means of scanning electron microscope(SEM), energy disperse spectroscopy(EDS), X-ray diffraction(XRD), nanoindentation tester and a home-made indentation system. The results indicated that with increasing copper content in the films, the micropores disappeared from the surface of Ti-Al-Si-N nanocomposite film and the compact films were obtained. A reduction of the grain size and a change of the (111) preferred orientation to (110) were observed. The microhardness of films increased from 14.76 GPa to 19.42 GPa. The elasticity modulus of Ti-Al-Si-Cu-N films with 1.72 at.% Cu content had the minimum value of 104.5 GPa. The incorporation of copper at high temperature had two effects, one was that the diffusion rate of Al element was advanced another was the crack of oxide layer was induced and the micropores were produced. Ti-Al-Si-N films had a better oxidation resistance than that of the films added Cu element.

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冯长杰,陈恩,吴娜梅,李明升,江鸢飞,袁烁. Cu含量对Ti-Al-Si-Cu-N纳米薄膜结构及高温抗氧化性能的影响[J].稀有金属材料与工程,2017,46(3):627~633.[fengchangjie, chenen, wunamei, limingsheng, jiangyuanfei, yuanshuo. Effects of Cu content on microstructure and high-temperature oxidation behavior of Ti-Al-Si-Cu-N nanocomposite films[J]. Rare Metal Materials and Engineering,2017,46(3):627~633.]
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  • 收稿日期:2014-11-27
  • 最后修改日期:2016-03-17
  • 录用日期:2016-03-29
  • 在线发布日期: 2017-05-18
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