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镝的分布对烧结和时效含镝钕铁硼永磁合金性能的影响
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山东大学材料液固结构演变与加工教育部重点实验室,山东大学材料液固结构演变与加工教育部重点实验室,烟台首钢磁性材料有限公司,烟台首钢磁性材料有限公司,烟台首钢磁性材料有限公司,山东大学材料液固结构演变与加工教育部重点实验室

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国家高技术研究发展计划 (SS2012AA030801);国家重点基础研究发展计划 (2010CB631203);大飞机关键构件成型共性技术研究 (2012ZX04010-081)


Distribution of Dysprosium and Influence on the Property of the Sintered and Aged Dy-doped NdFeB Permanent Magnets
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    摘要:

    本文研究了烧结和时效含镝钕铁硼磁体。通过对不同状态磁体的磁滞曲线,场发射电镜以及能谱分析对磁体的磁性能,微结构以及成份进行了分析。结果表明,除了主晶相外,镝元素主要分布在富钕相,钕镝氧化物和位于晶界的富镝颗粒中。优化时效过程促进了镝在磁体中合理的扩散以及分布,镝在烧结磁体,高温时效磁体以及优化时效磁体中富钕相,钕镝氧化物以及含镝颗粒中的含量减少,证明了优化时效后,镝元素在磁体中的合理分布,导致了含镝钕铁硼永磁合金矫顽力的提高。

    Abstract:

    Sintered and aged Dy-doped NdFeB magnets was studied in this work. The magnetic properties, microstructures and compositions was investigated by hysteresis loop instrument, thermal field emission scanning electron microscopy and energy disperse spectroscopy, respectively. The result of analysis indicated that Dy element mainly distributed in the Nd-rich phase, Nd-Dy oxides and Dy-rich particles which is located at the grain boundary of the sintered magnets, in addition to the main crystal phase Nd2Fe14B. The optimized aging process is beneficial to promote a reasonable diffusion and distribution for Dy element. The Dy contents of Nd-riched phases, Nd-Dy oxide, and Dy-riched particle decreased successively in the sintered, the high temperature aged and the optimal two-stage aged Dy-doped NdFeB permanent magnets. The measurements demonstrated that the enhancement of the coercivity of the aged Dy-doped NdFeB Magnet was caused mainly by the Dy element reasonable distribution.

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王晓丽,赵利娜,丁开鸿,崔胜利,孙永聪,李木森.镝的分布对烧结和时效含镝钕铁硼永磁合金性能的影响[J].稀有金属材料与工程,2016,45(2):309~314.[wangxiaoli, Zhao lina, Ding kaihong, Cui Shengli, Sun Yongsong, Li Mu-Sen. Distribution of Dysprosium and Influence on the Property of the Sintered and Aged Dy-doped NdFeB Permanent Magnets[J]. Rare Metal Materials and Engineering,2016,45(2):309~314.]
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  • 收稿日期:2015-01-30
  • 最后修改日期:2015-03-03
  • 录用日期:2015-05-13
  • 在线发布日期: 2016-07-19
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