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贫铀表面阴极微弧电沉积氧化铝涂层的研究
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表面物理与化学重点实验室,表面物理与化学重点实验室,中国工程物理研究院,表面物理与化学重点实验室,表面物理与化学重点实验室

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Study of Alumina Coating Deposited on Depleted Uranium Surface by Cathodic Microarc Method
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Science and Technology on Surface Physics and Chemistry Laboratory,Science and Technology on Surface Physics and Chemistry Laboratory,China Academy of Engineering Physics,Science and Technology on Surface Physics and Chemistry Laboratory,Science and Technology on Surface Physics and Chemistry Laboratory

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    摘要:

    以1.0mol.L-1Al(NO3)3.9H2O的乙醇溶液为电解液,用阴极微弧电沉积的方法在贫铀表面制备出厚度约为65μm的氧化铝陶瓷涂层,通过扫描电子显微镜(SEM)观察了涂层的表面和截面形貌,通过X射线衍射仪(XRD)及X射线能量色散谱(EDS)分析了涂层的成分以及相组成,通过电化学综合测试系统分析了涂层的电化学腐蚀性能,结果表明:涂层表面粗糙多孔,与基体呈犬牙咬合状结合;涂层主要由α-Al2O3和γ- Al2O3组成;涂层中含有少量的U元素,表明膜/基界面附近的贫铀基体在微弧放电的作用下也参与了成膜;沉积氧化铝涂层后,样品的腐蚀电流密度降低了2个数量级,耐腐蚀性能得到大幅度提高。

    Abstract:

    An alumina coating with a thickness of 65μm was prepared on depleted uranium surface by cathodic microarc desposition in 1mol/L Al(NO3)3.9H2O ethanol solution. The morphology, composition and phase constituent of alumina coating were analyzed by SEM, XRDand EDS. The corrosion resistance were determined by electrochemical integrated test system. The results show that the coating, which is composed of α-Al2O3and γ- Al2O3, remain a good adhesion to depleted uranium substrate. The coating contains a little uranium element, which confirms that depleted uranium substrate near the coating /uranium also takes part in the sintering process of coating under cathodic microarc discharge. The coating reduce the depleted corrosion current by two orders-of-magnitude, which shows the good corrosion resistance.

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王佳佳,帅茂兵,何伟波,莫川,蒋春丽.贫铀表面阴极微弧电沉积氧化铝涂层的研究[J].稀有金属材料与工程,2017,46(6):1727~1730.[Wang Jiajia, Shuai Maobing, He Weibo, Mo Chuan, Jiang Chunli. Study of Alumina Coating Deposited on Depleted Uranium Surface by Cathodic Microarc Method[J]. Rare Metal Materials and Engineering,2017,46(6):1727~1730.]
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  • 收稿日期:2015-02-12
  • 最后修改日期:2015-04-15
  • 录用日期:2015-06-11
  • 在线发布日期: 2017-11-07
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