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Nb-Ni-Ti系低Ni侧1000℃相平衡研究
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东北大学 材料各向异性与织构教育部重点实验室,东北大学 材料各向异性与织构教育部重点实验室,东北大学 材料各向异性与织构教育部重点实验室,东北大学 材料各向异性与织构教育部重点实验室,东北大学 材料各向异性与织构教育部重点实验室

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TG113.14

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国家自然科学基金资助(项目号50971037),辽宁省高校重点实验室支持计划资助(项目号LS2010062)


Phase equilibria of the low-Ni side in Nb-Ni-Ti System at 1000℃
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Key Laboratory for Anisotropy and Texture of Materials,Ministry of Education,Northeastern University,Key Laboratory for Anisotropy and Texture of Materials,Ministry of Education,Northeastern University,Key Laboratory for Anisotropy and Texture of Materials,Ministry of Education,Northeastern University,Key Laboratory for Anisotropy and Texture of Materials,Ministry of Education,Northeastern University,Key Laboratory for Anisotropy and Texture of Materials,Ministry of Education,Northeastern University

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    摘要:

    利用SEM,EPMA,XRD和DSC,对Nb-Ni-Ti系低Ni侧1000℃的液相相关相平衡进行了研究。结果表明,1000℃时,在Nb-Ni-Ti系低Ni侧存在着一个可与(Nb,betaTi)连续固溶体和TiNi化合物相平衡的液相区;该液相区源自Ti-Ni二元系,延伸至含Nb量3.7% (原子分数,下同)。而二元化合物TiNi在1000℃时则可以溶解约8.0%Nb。1000℃时,Nb-Ni-Ti系低Ni侧等温截面相图中存在两个三相区Liquid+(Nb,betaTi) TiNi和(Nb,betaTi) TiNi XB,XB是成分约为34.0Nb-44.9Ni-21.1Ti%的六方结构化合物;这两个三相区之间则是宽阔的(Nb,betaTi) TiNi两相区。在该两相区内,连续固溶体(Nb,betaTi)中的Ni含量变化不大、约为3%,Ti含量的变化范围约为6.6~39.9%。而3.7%Nb的溶入未能使二元化合物Ti2Ni相的稳定存在温度提高到1000℃。

    Abstract:

    The phase equilibria related with the liquid phase at 1000℃ in low-Ni side of the Nb-Ni-Ti system have been investigated by SEM, EPMA, XRD and DSC. It has been shown that there exists the liquid phase which could be in equilibrium with the continuous solid solution (Nb,betaTi) and compound TiNi in the low-Ni side of the Nb-Ni-Ti system at 1000℃. The liquid phase field originates from binary Ti-Ni system and extends to the 3.7%Nb (atomic fraction). The solid solubility of Nb in the compound TiNi is about 8.0%. At 1000℃, there are two three-phase fields consisting of Liquid+(Nb,betaTi) TiNi and (Nb,betaTi) TiNi XB in the Nb-Ni-Ti system, XB is the compound with the composition of 34.0Nb-44.9Ni-21.1Ti% and hexagonal structure. The broad two-phase field (Nb,betaTi) TiNi exists between the two three-phase fields. In this two-phase field, the Ni content in the continuous solid solution (Nb,betaTi) is about 3%, but the Ti content varies from 6.6 to 39.9%. The thermo-stability of the compound Ti2Ni has been improved by the solution of Nb atoms, but the Ti2Ni with 3.7%Nb could not exist at 1000℃.

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李志超,李洪晓,任玉平,蒋敏,秦高梧. Nb-Ni-Ti系低Ni侧1000℃相平衡研究[J].稀有金属材料与工程,2017,46(7):1875~1880.[LI Zhichao, LI Hongxiao, REN Yuping, JIANG Min, QIN Gaowu. Phase equilibria of the low-Ni side in Nb-Ni-Ti System at 1000℃[J]. Rare Metal Materials and Engineering,2017,46(7):1875~1880.]
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  • 收稿日期:2015-03-27
  • 最后修改日期:2015-04-23
  • 录用日期:2015-06-11
  • 在线发布日期: 2017-11-14
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