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不同掺杂Mo含量对CrMoN薄膜耐腐蚀性能的影响研究
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1.广西信息材料重点实验室 广西 桂林 5410042.桂林电子科技大学材料学院 广西 桂林 541004,1.广西信息材料重点实验室 广西 桂林 5410042.桂林电子科技大学材料学院 广西 桂林 541004

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TP383

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Study on influence of different Mo content on corrosion resistance of CrMoN coatings
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GUILIN UNIVERSITY OF ELECTRONIC TECHNOLOGY,

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    摘要:

    利用多弧离子镀技术,在4Cr13不锈钢表面制备CrN薄膜,并掺杂不同含量的Mo原子,制备CrMoN复合薄膜。用XRD、附着力划痕仪、显微硬度计和电化学测量仪分别检测复合薄膜的相结构、结合力、硬度以及在3.5% NaCl溶液、1 mol?L-1 NaOH溶液和1 mol?L-1 H2SO4溶液中的电化学腐蚀性能。结果表明;CrMoN复合薄膜形成了以NaCl型面心立方CrN结构为基础的(Cr,Mo)N结构;当Mo含量达到31.08%时,在(311)、(111)方向上出现Mo2N的衍射峰,此时薄膜出现了CrN、(Cr,Mo)N和Mo2N相结构并存的情况。当Mo的原子百分比为7.09% 时,结合力最大为57N,显微硬度达到最大值2962.3 HV;当Mo含量为14.26%时,在H2SO4溶液和NaOH溶液中耐蚀性能最好;当Mo含量为5.15%时,在NaCl溶液中耐蚀性能最好。复合薄膜腐蚀机理主要是局部腐蚀中的小孔腐蚀,缝隙腐蚀和电偶腐蚀也会发生。

    Abstract:

    CrMoN coatings were deposited with different Mo content on 4Cr13 stainless steel by multi-arc ion plating (MAIP). The binding force, hardness and corrosion resistance properties of CrMoN coatings were respectively investigated by adhesion scratch tester, hardness instrument, and electrochemical measuring instrument. The corrosion solution concentration were in 3.5% NaCl solution, 1 mol?L-1 NaOH solution and 1 mol?L-1 H2SO4 solution. Influence of different Mo content on corrosion resitance of CrMoN coatings was investigated. The result indicate that: NaCl-type fcc-phased (Cr, Mo)N were observed; when the Mo content achieved to 31.08%, diffraction peak of Mo2N was observed in the direction of (200), the coatings are always composed of three phases CrN, (Cr,Mo)N and Mo2N. When the Mo content achieve to 7.09%, the biggest binding force and micro-hardness are respectively 57 N, 2962.3 HV; When the Mo content achieve to 14.26%, the corrosion resistance of CrMoN coatings is the best in 1 mol?L-1 NaOH solution and 1 mol?L-1 H2SO4 solution; When the Mo content achieve to 5.15%, the corrosion resistance of CrMoN coatings is the best in 3.5% NaCl solution; Corrosion mechanism of coatings is mainly pitting corrosion, and crevice and galvanic corrosion occue.

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宋沂泽,高原.不同掺杂Mo含量对CrMoN薄膜耐腐蚀性能的影响研究[J].稀有金属材料与工程,2017,46(11):3503~3507.[song yize, gao yuan. Study on influence of different Mo content on corrosion resistance of CrMoN coatings[J]. Rare Metal Materials and Engineering,2017,46(11):3503~3507.]
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  • 收稿日期:2015-08-27
  • 最后修改日期:2016-03-13
  • 录用日期:2016-03-29
  • 在线发布日期: 2017-12-13
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