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电场强度对Ti纳米晶薄膜生长模式及性能的影响
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西安理工大学材料科学与工程学院,西安理工大学材料科学与工程学院/南京工业大学材料与工程学院,南昌大学材料科学与工程学院材料科学研究所,南京工业大学材料与工程学院,南京工业大学材料与工程学院

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TB303

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国家自然科学资助(项目号52171144)


Influence of Electric Field Intensity on the Growth Mode and Properties of Nanocrystalline Ti films
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xi'an university of technology,,,,

Fund Project:

Xinjiang Uygur Autonomous Region University Scientific Research Project (XJEDU2012I05); National Natural Science Foundation of China (21162027, 21063013)

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    摘要:

    采用强脉冲电场条件下物理气相沉积的方法,通过大幅提高脉冲峰值电流的方式,获得晶粒尺寸细小的Ti纳米晶薄膜,并依次对薄膜的生长模式及相关性能进行了对比研究。结果表明:较大的峰值电流可以获得晶粒尺寸细小的Ti纳米晶薄膜,但峰值电流的增大不能改变薄膜内晶体以Ti(100)晶面择优生长。薄膜的表面生长形貌表现为随峰值电流的增大,颗粒间隙大幅降低、粒子团聚尺寸增大、整体呈现圆球状紧密生长的结构。截面生长形貌表现为随峰值电流的增大逐渐由纤维状向柱状形貌过渡,并有效降低薄膜的内部缺陷,致密度显著提高。力学性能表现为随峰值电流的增大,薄膜的硬度,模量都呈现出先增大后减小的变化趋势,且当峰值电流增大到30A-45A之间时,Ti薄膜的硬度与模量存在最大值。

    Abstract:

    The nanocrystalline Ti films were deposited by the method of physical vapor deposition in high pulse electric field, the grain size of which was obtained by a sharp increase in the peak current to investigate the effects of the films growth mode and mechanical properties. The results show that the larger peak current could obtained the small grain size but cannot change the crystal surface preferential growth of Ti (100) crystal in the films. However, the film surface morphology showed the increase of the particle aggregation size and greatly reduce of the particle clearance while the peak current increased, the whole structure is showing a spherical close growth. The shape of the cross section of the film growth morphology is gradually changed from the fiber to columnar shape, and it can effectively reduce the film defects and increase the density with the increase of peak current. The hardness and modulus of the films increased firstly and then decreased with the increase of the peak current, the highest value appeared between 30A-45A of the peak current.

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乔泳彭,蒋百灵,曹政,李洪涛,刘燕婕.电场强度对Ti纳米晶薄膜生长模式及性能的影响[J].稀有金属材料与工程,2017,46(11):3428~3432.[Qiao Yongpeng, Jiang Bailing, Cao Zheng, Li Hongtao, Liu Yanjie. Influence of Electric Field Intensity on the Growth Mode and Properties of Nanocrystalline Ti films[J]. Rare Metal Materials and Engineering,2017,46(11):3428~3432.]
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  • 收稿日期:2015-09-08
  • 最后修改日期:2016-02-14
  • 录用日期:2016-03-29
  • 在线发布日期: 2017-12-13
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