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TiC含量对W-30Cu/TiC复合材料显微组织和性能影响研究
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合肥工业大学材料科学与工程学院,合肥工业大学材料科学与工程学院,合肥工业大学材料科学与工程学院,合肥工业大学材料科学与工程学院,合肥工业大学材料科学与工程学院

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Influence of TiC content on microstructure and properties of W–30Cu/TiC composites
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School of Materials Science and Engineering,Hefei University of Technology,School of Materials Science and Engineering,Hefei University of Technology,School of Materials Science and Engineering,Hefei University of Technology,School of Materials Science and Engineering,Hefei University of Technology,School of Materials Science and Engineering,Hefei University of Technology

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    摘要:

    经简化预处理后,采用化学法制得W–30Cu/(0-4) wt.% TiC复合粉末,在400MPa的压力下将制得的复合粉末压制成毛坯块体试样,随后在1300 °C下烧结1 h制得块体复合材料试样。采用场发射扫描电子显微镜来表征原始W 和TiC粉末、预处理后的W和TiC粉末、化学法制得的W–30Cu/(0, 0.25, 0.5, 1, 2, 3, 4) wt.% TiC复合粉末的显微形貌,以及制得的W–30Cu/TiC复合材料的显微结构。本文对不同TiC含量对W–30Cu/TiC复合材料的性能(如相对密度、硬度、导电性和抗弯强度等)进行研究。结果表明:对简单预处理后的W、TiC粉末化学镀Cu所获得的W–30Cu/TiC复合粉末的显微结构均匀。TiC含量低于1%时,W–30Cu/TiC复合材料的抗弯强度和硬度随TiC含量的增加而显著增大。而导电性则随TiC含量增加而减小,但仍高于国家标准值。添加一定量的TiC有利于获得综合性能能较好的W–30Cu/TiC复合材料。

    Abstract:

    W–30Cu/(0-4) wt.% TiC composite powders were prepared by electroless plating with simplified pretreatment. The composite powders were formed by cold compaction under 400 MPa using tablet machine and green compactions were sintered at 1,300 °C for 1 h. Micromorphology of the original W and TiC powders, simple-treated W and TiC powders, and as-received W–30Cu/(0, 0.25, 0.5, 1, 2, 3, 4) wt.% TiC composite powders after electroless plating were characterized by field emission scanning electron microscopy (FE-SEM). Microstructures of the W–30Cu/(0, 0.25, 0.5, 1, 2, 3, 4) wt.% TiC composites were also investigated by FE-SEM. The effect of TiC content on the properties of W–30Cu/(0, 0.25, 0.5, 1, 2, 3, 4) wt.% TiC composites ( such as relative density, hardness, electrical conductivity, and compressive strength) were studied. Results showed that W–30Cu/TiC composite powders with uniform structure were obtained by simplified W and TiC powder pretreatment, followed by electroless copper plating. When TiC content was less than 1wt%, the compressive strength and hardness of composite materials obviously increased and the electrical conductivity of composite materials decreased with TiC content increased, respectively. However, the electrical conductivity of composite materials was still higher than that of the national standard value. Adding a certain amount of TiC content to W–30Cu/(0, 0.25, 0.5, 1, 2, 3, 4) wt.% TiC composites, the composite materials exhibited good comprehensive performance.

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谌景波,黄丽枚,罗来马,昝祥,吴玉程. TiC含量对W-30Cu/TiC复合材料显微组织和性能影响研究[J].稀有金属材料与工程,2018,47(2):447~451.[Jingbo Chen, Limei Huang, Laima Luo, Xiang Zan, Yucheng Wu. Influence of TiC content on microstructure and properties of W–30Cu/TiC composites[J]. Rare Metal Materials and Engineering,2018,47(2):447~451.]
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  • 收稿日期:2016-04-11
  • 最后修改日期:2016-07-15
  • 录用日期:2016-09-14
  • 在线发布日期: 2018-03-15
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