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锆硼化物增强铌钼固溶体基复合材料的制备和性能的实验研究
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华北电力大学能源动力与机械工程学院,,华北电力大学能源动力与机械工程学院,华北电力大学能源动力与机械工程学院,华北电力大学能源动力与机械工程学院

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TG148

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国家自然科学基金项目(面上项目,重点项目,重大项目)


An experimental study on preparation and properties of Zirconium boride reinforced NbMo-matrix composites
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The National Natural Science Foundation of China (General Program, Key Program, Major Research Plan)

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    摘要:

    用热压烧结法,在30MPa压力,1600℃,Ar气氛保护状态下,设定两种保温时间,烧结制成了锆硼化物增强铌钼固溶体基复合材料。两种材料的原始成分分别是 42.5%Nb+42.5%Mo+15%ZrB2 (体积分数)和 42.5%Nb+42.5%Mo+10.5%ZrB2+4.5% SiC (体积分数)。使用扫描电镜、能谱仪、X射线衍射法测定了微观结构和相组成,使用显微硬度计和液压式万能试验机测定机械性能。实验观察到,在铌钼固溶体基体上均匀分布着ZrB颗粒。未发现SiC颗粒。两种材料最大的抗压强度与铌钼固溶体基体1380.15MPa相比,提高到了1974.17MPa。屈服强度提高到了1664.13MPa,硬度也是铌钼固溶体基体的3~5倍。复合材料强度和硬度的提高主要是因为固溶强化机制以及ZrB颗粒与铌钼固溶体基体良好的结合性。

    Abstract:

    Zirconium boride reinforced NbMo-matrix composites with a composition of 42.5%Nb+42.5%Mo+15%ZrB2 (Vol.%) and SiC doped with a composition of 42.5%Nb+42.5%Mo+10.5%ZrB2+4.5% SiC (Vol.%) was fabricated by hot-pressing under an uniaxial load of 30 MPa at 1600℃ in Ar atmosphere with two kind of holding time. The microstructure and phase compositions were analyzed by means of scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS) and X-ray diffraction (XRD). The mechanical properties were measured by Micro Vickers and hydraulic universal tester. NbMo solid solution was observed with small ZrB particles distributed uniformly in it. No SiC particle was founded. The compressive strength was improved to 1974.17MPa compared to the NbMo solid solution 1380.15MPa. The yield stress was improved to 1664.13MPa and the hardness was 3~5 times higher than NbMo. The increase in strength and hardness of the composites is a consequence of the solid solution strengthening mechanism and the excellent interface bonding between ZrB and Nb-Mo solid solution.

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王琦,刘宗德,胡慧东,高远,王永田.锆硼化物增强铌钼固溶体基复合材料的制备和性能的实验研究[J].稀有金属材料与工程,2017,46(9):2433~2436.[Qi Wang, Zongde Liu, Huidong Hu, Yuan Gao, Yongtian Wang. An experimental study on preparation and properties of Zirconium boride reinforced NbMo-matrix composites[J]. Rare Metal Materials and Engineering,2017,46(9):2433~2436.]
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历史
  • 收稿日期:2016-06-01
  • 最后修改日期:2017-09-10
  • 录用日期:2017-02-21
  • 在线发布日期: 2017-11-29
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