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单一立方相致密ReO3块材的烧结制备
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作者单位:

中国科学院物理研究所

中图分类号:

O469

基金项目:

国家重点研发计划(2017YFA0303600);基金委(11634016 11474334);中国科学院战略性先导科技专项(B类)(XDB07030100)


Synthesis of the single cubic phase, dense ReO3 bulk by sintering
Author:
Affiliation:

Institute of Physics,Chinese Academy of Sciences

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    摘要:

    ReO3具有相对简单的结构以及优良的导电性,在固态电池、电致变色以及液晶等器件中具有巨大的应用潜力,对表面科学、分析化学、生物物理学等领域都具有重要研究价值。但是由于铼氧化物复杂的相图结构,目前实验上制备高质量的单一立方相ReO3材料还极具挑战性。本文采用直接烧结的方式将ReO3粉末压片制备成块材,并结合X射线衍射(XRD)、电输运、扫描电子显微镜(SEM)等表征手段优化了最佳烧结条件,获得了纯立方相、结晶均匀、致密的ReO3片状材料。初步的生长实验表明,该方法制备的材料可以用作脉冲激光沉积的靶材,为生长高质量ReO3薄膜的工作打下了基础。

    Abstract:

    Rhenium trioxide (ReO3) has great application potential in solid-state batteries, electrochromic and liquid crystal devices owing to its relatively simple structure and high conductivity. It is also an important material for the fundamental studies in surface science, analytical chemistry, biophysics etc. However, the complicated phase diagram of rhenium oxides brings critical challenges to the synthesis of single-phased cubic ReO3 materials. In this paper, we synthesize ReO3 bulk by direct sintering of the pressed chips of ReO3 powders under the ambient pressure. With the characterizations of X-ray diffraction (XRD), electric transport and scanning electron microscope (SEM), we optimize the sintering temperature and time, and obtain the ReO3 materials in monophase of the cubic structure, with high crystalline homogeneity and high density. Preliminary growth experiments demonstrate that the obtained ReO3 can be used as the target in pulsed laser deposition technology, promising for future researches on the high-quality ReO3 films.

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朱 清,杨 芳,郭建东.单一立方相致密ReO3块材的烧结制备[J].稀有金属材料与工程,2020,49(1):349~454.[ZHU Qing, YANG Fang, GUO Jiandong. Synthesis of the single cubic phase, dense ReO3 bulk by sintering[J]. Rare Metal Materials and Engineering,2020,49(1):349~454.]
DOI:10.12442/j. issn.1002-185X.20181053

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  • 收稿日期:2018-10-16
  • 最后修改日期:2019-01-23
  • 录用日期:2019-02-21
  • 在线发布日期: 2020-02-16