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等离子烧结温度对CoCrCuFeNi高熵合金组织及性能影响
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1.东北大学;2.西北有色金属研究院;3.西安石油大学;4.西安科技大学;5.西安稀有金属材料研究院有限公司

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国家自然科学基金资助(51901192),陕西省重点研发计划(2019GY-164)


Spark Plasma Sintering Effect on Microstructure and Properties of CoCrCuFeNi High Entropy Alloy
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1.School of Materials Science and Engineering,Northeastern University;2.Northwest Institute for Nonferrous Metal Research,Xi’an

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    摘要:

    本文通过氩气雾化制备CoCrCuFeNi球形粉末,随后在900℃、1000℃、1100℃、1150℃温度下通过放电等离子活化烧结(Spark plasma sintering,SPS),成功制备CoCrCuFeNi高熵合金块体。结果表明:随着烧结温度的升高,材料室温抗拉强度先降低后升高,均匀却延伸率先大幅度提高,随后降低;当烧结温度为1100℃时,材料屈服强度和抗拉强度分别达到379.3MPa和655.6MPa,断后延伸率达21.9%;当烧结温度超过1100℃时,开始出现局部熔化现象,材料内部出现元素明显偏析现象。烧结温度为900℃时,拉伸断口沿球形粉末表面脆性断裂,随着烧结温度提高,断口转变为包含韧窝的韧性断裂。由于高温烧结过程中基体内发生渗碳现象,透射电镜结果表明碳与基体发生反应,形成第二相碳化物。

    Abstract:

    In this paper, CoCrCuFeNi high-entropy alloy was successfully fabricated by spark plasma sintering (SPS) at 900 oC, 1000 oC, 1100 oC and 1150 oC. The tensile at room temperature results shows that the tensile strength of the CoCrCuFeNi alloy firstly decreases and then increase with the increase of sintering temperature. However, the uniform elongation firstly significantly increases and then decreases. When the sintering was carried out at 1100 oC, the yield strength and unltimate tensile strength of CoCrCuFeNi alloy reaches 379.3 MPa and 655.6 MPa, respectively, and the elongation after fracture is 21.9%. When sintering temperature above 1100 oC, the element segregation obviously appears in the material because of the local melting. Besides, the tensile fracture is brittle feature along the surface of the spherical powder at 900℃. While the fracture is a ductile fracture as the sintering temperature increases. Because of the diffusion of carbon atom during high temperature sintering, TEM results show that the carbon reacts with the matrix to form second phase carbide particles inside the matrix.

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夏洪勇,董龙龙,霍望图,田宁,周悦,赵盘巢,周廉,张于胜.等离子烧结温度对CoCrCuFeNi高熵合金组织及性能影响[J].稀有金属材料与工程,2021,50(9):3327~3334.[Xia Hongyong, Dong Longlong, Huo Wangtu, Tian Ning, Zhou Yue, Zhao Panchao, Zhou Lian, Zhang Yusheng. Spark Plasma Sintering Effect on Microstructure and Properties of CoCrCuFeNi High Entropy Alloy[J]. Rare Metal Materials and Engineering,2021,50(9):3327~3334.]
DOI:10.12442/j. issn.1002-185X.20200780

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历史
  • 收稿日期:2020-10-10
  • 最后修改日期:2020-12-18
  • 录用日期:2020-12-22
  • 在线发布日期: 2021-09-27
  • 出版日期: 2021-09-24