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淬火温度对超高强Al-Zn-Mg-Cu合金组织和与性能的影响
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中国航空制造技术研究院

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国防基础科研计划资助(项目号JCKY2017205B032),国防科技创新特区项目,国家自然科学No. 51971206.


Effect of quench temperature on the microstructure and properties of the ultra-high strength Al-Zn-Mg-Cu alloy
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1.AVIC Manufacturing Technology Institute,Beijing,100024;2.China

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    摘要:

    强度接近800MPa的超高强Al-Zn-Mg-Cu合金在航空工业上拥有广阔的应用前景,对结构轻量化具有重要意义,但较差的耐蚀性能限制了该合金的应用。本文通过控制淬火用的水介质温度(简称淬火温度),在超高强Al-Zn-Mg-Cu合金晶间形成淬火析出相来调控耐腐蚀性能。研究对比了经不同温度淬火后的峰时效态微观组织、拉伸力学性能、晶间腐蚀性能以及剥落腐蚀性能,发现:提高淬火温度有助于形成晶内与晶间淬火析出相,促进时效析出相断续分布,并提高了晶间析出相中Cu元素含量;当淬火温度升高至80℃,室温拉伸强度性能仅下降了1.4%,但晶间腐蚀深度降低了约50%,剥落腐蚀由ED级优化为PC-EA级,但继续增加淬火温度则降低耐蚀性能。分析认为,淬火温度在60-80℃之间时,晶界区域形成的淬火析出相提高了晶界电位,阻断了腐蚀扩展通道,同时由于晶内淬火析出相的数量较少,在不显著降低力学性能的前提下提高了耐腐蚀性能。

    Abstract:

    The ultra-high strength Al-Zn-Mg-Cu alloy with strength of 800MPa has a promising application prospect in the aviation industry, and also a great effect on the structural lightweight, however, its application is limited at present due to its poor corrosion resistance. In this paper, the corrosion resistance of ultra-high strength Al-Zn-Mg-Cu alloy was controlled by controlling the quenching temperature of the colling water (quenching temperature for short). The microstructure, tensile mechanical properties, intergranular corrosion properties and exfoliation corrosion properties of the alloy after ageing were compared. It is found that increasing the quenching temperature promoted the formation of the intragranular and intergranular precipitates, and also promoted the intermittent distribution of the aged precipitation and the content of Cu in intergranular precipitations. The tensile strength at room temperature decreased by only 1.4%, but the intergranular corrosion depth decreased by about 50%. The exfoliation corrosion decreases from ED grade to PA-EA grade when the quenching temperature increased to 80 ℃, but decreased when exceeds 80 ℃. The analysis belives that when the proper quenching temperature is between 60 ℃ and 80 ℃, in which the precipitations increase the grain boundary potential and block the corrosion propagation channel. At the same time, the number and size of precipitations can be controlled, which didn’t cause significantly reducing of the mechanical properties.

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韩宝帅,曾元松,徐严谨,马晓光,韩秀全.淬火温度对超高强Al-Zn-Mg-Cu合金组织和与性能的影响[J].稀有金属材料与工程,2022,51(4):1378~1384.[Baoshuai Han, Yuansong Zeng, Yanjin Xu, Xiaoguang Ma, Han Xiuquan. Effect of quench temperature on the microstructure and properties of the ultra-high strength Al-Zn-Mg-Cu alloy[J]. Rare Metal Materials and Engineering,2022,51(4):1378~1384.]
DOI:10.12442/j. issn.1002-185X.20210292

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  • 收稿日期:2021-04-04
  • 最后修改日期:2021-06-07
  • 录用日期:2021-06-21
  • 在线发布日期: 2022-05-05
  • 出版日期: 2022-04-28