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微量Gd添加对Mg-8Zn-1Mn-3Sn合金组织转变及性能的影响
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作者单位:

1.重庆大学 材料科学与工程学院,重庆 400044;2.重庆大学 国家镁合金材料工程技术研究中心,重庆 400044

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基金项目:

高强韧镁合金设计与大规格锭坯制备(2016YFB0301101);重庆市科学与前沿研究技术专项项目 (cstc2019jscx-mbdxX0033)


Effect of Minor Gd Addition on Microstructure Evolution and Properties of As-cast Mg-8Zn-1Mn-3Sn Alloy
Author:
Affiliation:

1.College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China;2.National Engineering Research Center for Magnesium Alloys, Chongqing University, Chongqing 400044, China

Fund Project:

National Great Engineering Research Project of China (2016YFB0301101); Chongqing Technology Innovation and Application Development Special Project (cstc2019jscx-mbdxX0033)

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    摘要:

    研究了微量Gd的添加对Mg-8Zn-1Mn-3Sn合金显微组织及性能的影响。结果表明,Mg-8Zn-1Mn-3Sn-xGd主要由α-Mg基体、MgZn2、Mg7Zn3、Mg2Sn相、MgSnGd相组成。MgSnGd相为高温相,在合金凝固过程中最先形成,改变了凝固过程,使晶界处半连续第二相转变为断网状。MgSnGd相与α-Mg基体存在共格位向关系,能作为异质形核核心细化合金晶粒。Mg-8Zn-1Mn-3Sn-0.5Gd合金的综合力学性能最佳,合金力学性能得到显著提高的机制为通过添加Gd元素细化晶粒组织、MgSnGd相钉扎晶界阻碍位错运动以及晶界第二相形貌转变。

    Abstract:

    The effect of minor Gd element on the microstructure and properties of Mg-8Zn-1Mn-3Sn alloy was studied. The results show that Mg-8Zn-1Mn-3Sn-xGd is mainly composed of α-Mg matrix, MgZn2, MgZn, Mg7Zn3, Mg2Sn phase and MgSnGd phase. The MgSnGd phase is a high temperature phase, which is formed firstly during the solidification and changes the solidification process, causing the semi-continuous second phase at the grain boundary to transform into a discontinuous network. The MgSnGd phase has a coherent orientation relationship with the α-Mg matrix, which can be used as a heterogeneous nucleation core to refine grains. The Mg-8Zn-1Mn-3Sn-0.5Gd alloy has the best comprehensive mechanical properties. The mechanical properties of the alloy are significantly improved by adding Gd elements to refine the grains, and the MgSnGd phase pins the grain boundary to hinder the movement of dislocations and the transformation of the second phase of the grain boundary.

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薛寒松,周扬,李鹤,王金阳,刘松,张丁非.微量Gd添加对Mg-8Zn-1Mn-3Sn合金组织转变及性能的影响[J].稀有金属材料与工程,2022,51(6):2011~2019.[Xue Hansong, Zhou Yang, Li He, Wang Jinyang, Liu Song, Zhang Dingfei. Effect of Minor Gd Addition on Microstructure Evolution and Properties of As-cast Mg-8Zn-1Mn-3Sn Alloy[J]. Rare Metal Materials and Engineering,2022,51(6):2011~2019.]
DOI:10.12442/j. issn.1002-185X.20210343

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  • 收稿日期:2021-04-19
  • 最后修改日期:2021-06-21
  • 录用日期:2021-07-09
  • 在线发布日期: 2022-06-29
  • 出版日期: 2022-06-29