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等离子喷涂热障涂层的热循环氧化行为研究
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中国航发上海商用航空发动机制造有限责任公司

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上海市青年科技启明星计划资助(项目号20QB1406200)


Study of thermal cycling behavior of plasma sprayed thermal barrier coating
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AECC Shanghai Commercial Aircraft Engine Manufacturing Co.,Ltd.

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    摘要:

    本文采用大气等离子喷涂在HA188合金基材上制备NiCrAlY+YSZ热障涂层,并进行了1100 oC、1120 oC和1150 oC三个温度点的高温循环氧化行为对比研究。结果表明,随着考核温度的升高,热障涂层热循环失效寿命显著下降,失效主要是由YSZ/NiCrAlY界面附近YSZ 层中裂纹形成和扩展导致。循环失效后的YSZ与制备态的相结构一样,均为非平衡四方相t"-ZrO2,未发生t"→c+m相变。在热循环过程中,YSZ/NiCrAlY界面形成的热生长氧化物层(Thermally Grown Oxide, TGO)增厚基本符合“抛物线”规律,并且YSZ中裂纹的产生和扩展与TGO的增厚直接相关。

    Abstract:

    NiCrAlY+YSZ thermal barrier coatings (TBCs) were deposited on HA188 alloy using air plasma spraying technique. The cyclic oxidation behavior of TBCs was studied at 1100 oC, 1120 oC and 1150 oC high temperature. The results indicated that TBCs lifetime significantly decreased with the increasing of thermal cyclic temperature. The failure of TBCs was attributed to the formation and propagation of crack in YSZ layer near the YSZ/NiCrAlY interface. XRD analysis indicated that the phase composition of YSZ top coat had no change during all thermal cyclic process, and kept the same metastable tetragonal-prime (t"-ZrO2) structure. It was proposed that thermally grown oxide (TGO) growth following a parabolic law had an important effect on the formation and propagation of crack in YSZ.

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薛文利,陆涛,黄佳华,张永志.等离子喷涂热障涂层的热循环氧化行为研究[J].稀有金属材料与工程,2022,51(7):2667~2672.[Xue Wenli, Lu Tao, Huang Jiahua, Zhang Yongzhi. Study of thermal cycling behavior of plasma sprayed thermal barrier coating[J]. Rare Metal Materials and Engineering,2022,51(7):2667~2672.]
DOI:10.12442/j. issn.1002-185X.20210560

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  • 收稿日期:2021-06-30
  • 最后修改日期:2021-11-10
  • 录用日期:2022-01-11
  • 在线发布日期: 2022-07-29
  • 出版日期: 2022-07-27