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预退火时间对半固态挤压铜合金组织及性能的影响
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昆明理工大学

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国家自然科学基金资助(项目号51965028,51665024),云南省基础研究计划项目(202001AT070031)


Effect of Pre-annealing Time on Microstructure and Properties of Semi-solid extruded Copper Alloy
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Kunming University of Science and Technology

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    摘要:

    用预退火-轧制-重熔应变诱导熔化激活法制备半固态浆料并进行反挤压成形制备铜合金轴套零件,研究预退火时间对铜合金轴套显微组织、硬度、力学性能的影响规律。结果表明:预退火时间对半固态铜合金轴套组织、力学性能、硬度的影响较大。预退火处理后ZCuSn10P1铜合金固相晶粒中Sn含量趋于均匀,700 ℃退火处理改善了ZCuSn10P1铜合金的元素偏析倾向。随着预退火时间增加,半固态铜合金轴套组织的平均晶粒尺寸逐渐增加,形状因子和液相率逐渐减小;轴套布氏硬度降低,抗拉强度和延伸率先增加后降低。综合性能较佳的预退火工艺为700 ℃退火2 h,此时ZCuSn10P1铜合金轴套组织均匀性好、元素分布更均匀,轴套平均晶粒尺寸为:73.06 μm,平均形状因子为0.72,抗拉强度为382 MPa,延伸率为5.5%,平均布氏硬度为127 HBW。

    Abstract:

    The pre-annealing-rolling-remelting strain-induced melting activation method was used to prepare semi-solid slurry and back-extrusion to prepare copper alloy bushing parts. The effect of pre-annealing time on the microstructure, hardness, and mechanical properties of copper alloy bushings has studied the law of influence. The results show that the pre-annealing time dramatically influences the structure, mechanical properties, and hardness of the semi-solid copper alloy bushing. After pre-annealing, the Sn content in ZCuSn10P1 copper alloy α-Cu tends to be uniform. Annealing at 700℃ improves the elemental segregation tendency of ZCuSn10P1 copper alloy. With the increase of annealing time, the average grain size of sleeve structure increases, shape factor decreases, and liquid phase ratio decreases; The Brinell hardness of the sleeve decreased, and the tensile strength and extension were increased first and then decreased. The pre-annealing process with better comprehensive properties is 700 ℃ for 2h. At this time, the microstructure uniformity and element distribution of the ZCuSn10P1 copper alloy sleeve are better, and the average grain size of the sleeve is 73.06 μm. The average shape factor is 0.72, tensile strength is 382 MPa, elongation is 5.5%, and average Brinell hardness is 127 HBW.

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肖 寒,陈 磊,张雄超,周瑀杭,陈 昊,崔鋆昕.预退火时间对半固态挤压铜合金组织及性能的影响[J].稀有金属材料与工程,2022,51(9):3435~3442.[Xiao Han, Chen Lei, Zhang Xiong Chao, Zhou Yu Hang, Chen Hao, Cui Yun Xin. Effect of Pre-annealing Time on Microstructure and Properties of Semi-solid extruded Copper Alloy[J]. Rare Metal Materials and Engineering,2022,51(9):3435~3442.]
DOI:10.12442/j. issn.1002-185X.20210760

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  • 收稿日期:2021-08-24
  • 最后修改日期:2021-09-15
  • 录用日期:2021-09-26
  • 在线发布日期: 2022-10-08
  • 出版日期: 2022-09-27