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AISI430铁素体不锈钢表面制备MnCo2O4涂层特性及内应力研究
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昆明理工大学材料科学与工程学院、云南昆明

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国家自然科学基金资助(项目号52161014 与 51665022)


Study on the characteristics and internal stress of MnCo2O4 coatings prepared on the surface of AISI430 ferritic stainless steel
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Faculty of Materials Science and Engineering,Kunming University of Science and Technology

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    摘要:

    为了探究MnCo2O4尖晶石涂层作为固体氧化物燃料电池的金属连接体表面涂层的性能,使用溶胶-凝胶法制备出纯净的前驱体粉末,再使用电泳沉积方法制备出致密的MnCo2O4尖晶石涂层,利用SEM、EDS和XRD等表征手段观察分析MnCo2O4尖晶石涂层的相结构和微观组织形貌。采用“四探针法”测量MnCo2O4尖晶石涂层800℃氧化200h前后的面比电阻使用拉拔法完成不同界面粗糙度下的涂层结合强度测试,并用有限元仿真加以验证。结果显示,MnCo2O4尖晶石涂层结构均匀,致密度较好。相较于AISI430不锈钢基体来说,在800℃空气中氧化200h,抗氧化性提高了接近3倍。且中温面比电阻小于SOFC金属连接体规定的极限值。此外,基体表面粗糙度可以有效的增加涂层与基体的机械咬合作用,但同时也会导致应力集中,出现缺陷,从而降低了结合强度。

    Abstract:

    In order to investigate the performance of MnCo2O4 spinel coating as a metal linker surface coating for solid oxide fuel cells, pure precursor powder was prepared by sol-gel method, and then dense MnCo2O4 spinel coating was prepared by electrophoretic deposition method. The four-probe method was used to measure the surface specific resistance of MnCo2O4 spinel coatings before and after oxidation at 800°C for 200 h. The bond strength of the coatings was tested at different interface roughnesses using the pull-out method and verified using finite element simulations. The results show that the MnCo2O4 spinel coating has a homogeneous structure and good densities. Compared to the AISI430 stainless steel substrate, oxidation at 800°C in air for 200h increases the oxidation resistance by nearly three times. And the specific resistance at the medium temperature surface is less than the limit value specified for SOFC metal connectors. In addition, the surface roughness of the substrate can effectively increase the mechanical bite between the coating and the substrate, but at the same time it can also lead to stress concentration and defects, which reduce the bond strength.

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卫书超,李明宇,詹肇麟. AISI430铁素体不锈钢表面制备MnCo2O4涂层特性及内应力研究[J].稀有金属材料与工程,2022,51(12):4697~4704.[Wei ShuChao, Li MingYu, Zhan ZhaoLin. Study on the characteristics and internal stress of MnCo2O4 coatings prepared on the surface of AISI430 ferritic stainless steel[J]. Rare Metal Materials and Engineering,2022,51(12):4697~4704.]
DOI:10.12442/j. issn.1002-185X.20211050

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历史
  • 收稿日期:2021-11-29
  • 最后修改日期:2022-01-28
  • 录用日期:2022-03-07
  • 在线发布日期: 2023-01-19
  • 出版日期: 2022-12-30