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高温热压法制备La(Fe, Si)13Hy系磁制冷材料的磁热性能研究
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1.西安理工大学;2.包头稀土研究院

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国家自然科学基金资助(项目号52066001), 内蒙自然科学基金资助(项目号2021MS05016), 北方稀土项目资助(项目号BFXT-2021-D-0013)


Research on the Magnetocaloric Effect of La(Fe, Si)13HyMagnetic Refrigeration Material Prepared by Hot-pressed Method at High Temperature
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1.Xi’an University of Technology,Xi’an;2.Baotou Research Institute of Rear earths

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    摘要:

    La(Fe, Si)13HY系合金是一种极具发展潜力的室温磁制冷材料,但该材料易粉化,如何成型并保持大磁热效应成为了亟需解决的问题。本文采用中频感应炉熔炼La0.8Ce0.2Fe11.51Mn0.19Si1.3母合金并退火,之后制备成粉末。合金粉末在650 ℃, 850 ℃和1050 ℃不同温度下热压成型,将热压块体合金加工成薄片后进行饱和氢化。利用X射线衍射仪、扫描电子显微镜、VersLab对样品的相组成、微观结构、磁热性能进行了研究。在1050 ℃下热压样品的孔隙率最低,最大体积磁熵变最高,达到了144.7 mJ/cm3?K。1050 ℃热压样品氢化后居里温度提高至室温附近,仍保持了一级磁相变的大磁热效应,且没有裂痕产生,保持了完整性。

    Abstract:

    La(Fe, Si)13HY based alloy is regarded as the candidate of the room temperature magnetic refrigeration materials. However as the poor mechanical property of the hydride which is difficult to be used in the magnetic refrigerator. How to prepare the magnetic refrigrant with large magnetocaloric effect is the key problem to be solved. In this paper La0.8Ce0.2Fe11.51Mn0.19Si1.3master alloy was prepared by medium frequency induction furnace and annealed, followed by milling to powder. The alloy podwer was hot pressed at 650 ℃, 850 ℃ and 1050 ℃ respectively. The resulted La0.8Ce0.2Fe11.51Mn0.19Si1.3alloy was cut into plates and then hydrogenated until saturated. The phase constitution, microstructure and magnetocaloric effect of samples was determined by XRD, SEM and VersLab. The porosity is the lowest and the volumetric magnetic entropy change is the alrgest (144.7 mJ/cm3?K) for the sample hot pressed at 1050 ℃. The Curie temperature increase to near room temperature, the large magnetocaloric effect of the first order phase transition is still maintained for the sample hot pressed at 1050 ℃ after hydrogenation. No cracks on the surface are found on the hydride and keep integrity.

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程娟,黄焦宏,游才印,李波,刘翠兰,郭亚茹.高温热压法制备La(Fe, Si)13Hy系磁制冷材料的磁热性能研究[J].稀有金属材料与工程,2023,52(1):318~322.[CHENG Juan, HUANG Jiaohong, YOU Caiyin, LI Bo, LIU Cuilan, GUO Yaru. Research on the Magnetocaloric Effect of La(Fe, Si)13HyMagnetic Refrigeration Material Prepared by Hot-pressed Method at High Temperature[J]. Rare Metal Materials and Engineering,2023,52(1):318~322.]
DOI:10.12442/j. issn.1002-185X.20211098

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  • 收稿日期:2021-12-10
  • 最后修改日期:2022-01-24
  • 录用日期:2022-02-09
  • 在线发布日期: 2023-02-13
  • 出版日期: 2023-02-08