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微量镍元素添加对Zr-4合金微观结构、耐腐蚀性能及吸氢行为的影响
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1.东莞材料基因高等理工研究院,广东 东莞 523808;2.国核宝钛锆业股份公司,陕西 宝鸡 721013

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广东省引进创新创业团队项目(编号:2016ZT06G025)


Effect of Trace Nickel Addition on Microstructure, Corrosion Resistance and Hydrogen Absorption of Zr-4 Alloy
Author:
Affiliation:

1.Centre of Excellence for Advanced Materials, Dongguan 523808, China;2.State Nuclear BaoTi Zirconium Industry Company, Baoji 721013, China

Fund Project:

Guangdong Innovative and Entrepreneurial Research Team Program (2016ZT06G025)

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    摘要:

    将微量镍元素合金化添加到Zr-4合金中,制备了合金板材试样。利用板材试样研究了微量镍元素的添加对Zr-4合金微观结构、耐腐蚀及吸氢性能的影响。结果表明,将镍元素含量由海绵锆原料中的0.001%(质量分数)以下添加至0.005%,可大幅提升其400 ℃蒸汽下耐腐蚀性能,同时对吸氢性能没有明显影响。微量镍元素的添加,不仅使Zr(Fe, Ni)2结构的第二相粒子明显增加,同时还促进了硅在第二相粒子周围的偏聚,这可以阻止或延缓细小第二相粒子被氧化的进程。进一步采用相同合金成分制备的锆管(Φ63.5 mm×10.92 mm),也呈现出了优异的耐疖状腐蚀和耐均匀腐蚀性能。

    Abstract:

    Nickel as a trace element was added into zirconium alloy (Zr-4) and then alloy sheet samples were prepared. The microstructure, corrosion property, and hydrogen content of the Zr-4 alloy were studied. Results show that the steam corrosion resistance at 400 °C can be greatly improved by adding nickel from 0.001wt% (the content in the sponge zirconium) to 0.005wt%, and there is no obvious effect on hydrogen absorption property. Trace nickel addition increases the content of the second phase particles in the form of Zr(Fe, Ni)2 obviously, and promotes the aggregation of silicon around second phase particles, which can prevent or delay the oxidation of fine particles. In addition, zirconium tubes (Φ63.5 mm×10.92 mm) with the same alloy component also exhibit excellent nodular corrosion resistance and uniform corrosion resistance.

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储林华,张书彦,袁改焕,吴桂毅.微量镍元素添加对Zr-4合金微观结构、耐腐蚀性能及吸氢行为的影响[J].稀有金属材料与工程,2022,51(12):4488~4495.[Chu Linhua, Zhang Shuyan, Yuan Gaihuan, Wu Guiyi. Effect of Trace Nickel Addition on Microstructure, Corrosion Resistance and Hydrogen Absorption of Zr-4 Alloy[J]. Rare Metal Materials and Engineering,2022,51(12):4488~4495.]
DOI:10.12442/j. issn.1002-185X.20220144

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历史
  • 收稿日期:2022-02-26
  • 最后修改日期:2022-12-02
  • 录用日期:2022-03-18
  • 在线发布日期: 2023-01-11
  • 出版日期: 2022-12-30