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人工时效和腐蚀介质浓度对2A97 Al-Cu-Li合金电化学腐蚀行为的影响
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安徽工业大学 机械工程学院,安徽 马鞍山 243032

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the Key Projects of Scientific Research in Colleges and Universities of Anhui Provincial Department of Education(KJ2021A036), Major Natural Science Research Project of Anhui Provincial Department of Education (KJ2016SD09) for supporting


Effects of Artificial Aging and Corrosion Medium Concentration on Electrochemical Corrosion Behavior of 2A97 Al-Cu-Li Alloys
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School of Mechanical Engineering, Anhui University of Technology, Ma'anshan 243032, China

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Key Projects of Scientific Research in Colleges and Universities of Anhui Provincial Department of Education (KJ2021A036); Major Natural Science Research Project of Anhui Provincial Department of Education (KJ2016SD09)

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    摘要:

    采用动电位极化曲线电化学方法研究了2A97-T3和2A97-T6 Al-Cu-Li合金的耐腐蚀性能,并以第3代典型2060-T8合金、2099-T83铝锂合金和航空用2024-T4高强铝合金为参考对象进行了比较。通过分析电化学参数和腐蚀形貌,发现合金在3种浓度的NaCl溶液中的耐腐蚀性为2A97-T3>2A97-T6>2024-T4>2060-T8>2099-T83。随着NaCl溶液浓度的增加,合金的腐蚀电位(ECorr)均降低,同时加剧了表面点蚀和晶间腐蚀程度。2A97-T3合金通过进行固溶和双级人工时效处理的共同作用得到2A97-T6合金,此时T1相数量大大增加且分布更加均匀。因此,热处理工艺降低了2A97铝合金的腐蚀电位,导致2A97-T6合金的耐腐蚀性能略弱于2A97-T3合金。晶间θ相的解体诱导了2A97-T3合金的剥落腐蚀形貌,而2A97-T6合金的点蚀形貌是由晶内T1相的溶解造成的。

    Abstract:

    The corrosion resistance of 2A97-T3 and 2A97-T6 Al-Cu-Li alloys was studied by the electrochemical method through potentiodynamic polarization curves. The typical third generation 2060-T8, 2099-T83, and 2024-T4 alloys were used as reference for comparison. Through the analysis of electrochemical parameters and corrosion morphology, the results reveal that the corrosion resistance of the alloys in NaCl solution of different concentrations is as follows: 2A97-T3>2A97-T6>2024-T4>2060-T8>2099-T83. With increasing the concentration of NaCl solution, the corrosion potential (ECorr) of all alloys is decreased. Moreover, the surface pitting and intergranular corrosion become severe. The T1 phase greatly increases with more uniform distribution in 2A97-T6 alloy, which is obtained from the 2A97-T3 alloy after the solid solution coupled with double-stage artificial aging treatment. Consequently, the heat treatment process reduces the corrosion potential of 2A97-T6 Al alloy, which leads to the slightly weaker corrosion resistance of 2A97-T6 Al alloy than that of 2A97-T3 alloy. The disintegration of the intergranular θ phase induces the exfoliation corrosion morphology of 2A97-T3 alloy, and the pitting morphology of 2A97-T6 alloy is caused by the dissolution of intragranular T1 phase.

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张鹏,赵新生,饶思贤.人工时效和腐蚀介质浓度对2A97 Al-Cu-Li合金电化学腐蚀行为的影响[J].稀有金属材料与工程,2023,52(5):1573~1582.[Zhang Peng, Zhao Xinsheng, Rao Sixian. Effects of Artificial Aging and Corrosion Medium Concentration on Electrochemical Corrosion Behavior of 2A97 Al-Cu-Li Alloys[J]. Rare Metal Materials and Engineering,2023,52(5):1573~1582.]
DOI:10.12442/j. issn.1002-185X.20220822

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  • 收稿日期:2022-10-19
  • 最后修改日期:2022-12-30
  • 录用日期:2022-12-30
  • 在线发布日期: 2023-05-31
  • 出版日期: 2023-05-29