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Y对新型Fe-Ni-Cr-Al合金高温氧化行为的影响
作者:
作者单位:

1.沈阳化工大学机械与动力工程学院;2.中国科学院金属研究所

基金项目:

国家重点研发计划(No.2021YFC2202402)


Effect of Yttrium on High Temperature Oxidation Behavior ofNew-Type Fe-Ni-Cr-Al Alloy
Author:
Affiliation:

1.School of Mechanical and Power Engineering,Shenyang University of Chemical Technology;2.Institute of Metal Research,Chinese Academy of Sciences

Fund Project:

National Key R&D Program of China (No.2021YFC2202402)

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    摘要:

    利用恒温氧化试验研究了不同Y含量的新型Fe-Ni-Cr-Al合金在1300 ℃空气中的氧化行为,采用X射线衍射仪器(XRD)和扫描电子显微镜(SEM)研究了氧化产物类型和分布。研究发现Y的添加有益于提高Fe-Ni-Cr-Al合金的抗氧化能力,其原因是由于Y元素的添加促进了Fe-Ni-Cr-Al合金表面形成致密的尖晶石和氧化铬的复合保护层,减缓了基体合金元素的扩散,同时,Y的加入促进了Al2O3由内氧化向外氧化的转变,减缓了合金内氮化进程,整体提高了合金的抗氧化性能。

    Abstract:

    The oxidation behaviors of new-type Fe-Ni-Cr-Al alloys with different Y contents in air atmosphere at 1300 ℃ were studied by isothermal oxidation test. The type and distribution of oxidation products were studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM). It is found that the addition of Y element is beneficial to the oxidation resistance of Fe-Ni-Cr-Al alloy. The reason is that the Y element can promote the formation of a dense composite protective layer of spinel and chromium oxide on the surface of Fe-Ni-Cr-Al alloy, and then slow down the diffusion of the elements in the matrix. At the same time, Y element can accelerate the transformation mode of Al2O3 from internal oxidation to external oxidation and slow down the internal nitridation process. In summary, the oxidation resistance increases.

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任雷,付广艳,刘恩泽,谭政,宁礼奎,来永军,佟健,李海英,郑志. Y对新型Fe-Ni-Cr-Al合金高温氧化行为的影响[J].稀有金属材料与工程,2023,52(11):3857~3866.[Ren Lei, Fu Guangyan, Liu Enze, Tan Zheng, Ning Likui, Lai Yongjun, Tong Jian, Li Haiying, Zheng Zhi. Effect of Yttrium on High Temperature Oxidation Behavior ofNew-Type Fe-Ni-Cr-Al Alloy[J]. Rare Metal Materials and Engineering,2023,52(11):3857~3866.]
DOI:10.12442/j. issn.1002-185X.20220838

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  • 收稿日期:2022-10-25
  • 最后修改日期:2022-11-25
  • 录用日期:2022-11-29
  • 在线发布日期: 2023-11-27
  • 出版日期: 2023-11-22