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紫铜在云南热带雨林土壤中的长期腐蚀行为
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1.电信科学技术第五研究所有限公司;2.成都泰瑞通信设备检测有限公司

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科技基础资源调查专项(项目号2021FY100603)


Long term Corrosion Behavior of Copper in Yunnan Tropical Rainforest Soil
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The Fifth Research Institute of telecommunications technology Co

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    摘要:

    本文采用失重法、形貌分析、成分分析和电化学测试等方法研究了紫铜管长期埋藏于热带雨林土壤环境中的腐蚀行为。结果表面,紫铜管埋藏16年后,平均腐蚀速率为2.5μm/y,腐蚀失重规律符合幂函数模型,其拟合方程为C=0.4273t-0.246。紫铜管表面腐蚀产物呈淡绿色的致密鳞状结构,与金属基体结合良好。 XPS、EDS和FTIR分析结果显示该腐蚀产物主要成分为铜绿(Cu2(OH)2CO3)。电化学测试结果表明,埋藏16年后,紫铜管腐蚀速率变小,阻抗值明显增大,表明腐蚀产物膜对基体形成良好的保护作用,能有效减缓腐蚀过程的继续发展。

    Abstract:

    The corrosion behavior of copper pipes buried in tropical rain forest soil environment for a long time was studied by weight-loss method, morphology analysis, composition analysis and electrochemical test in this paper. The results show that the average corrosion rate of the copper pipe after 16 years of burial is 2.5 μm/y, the law of corrosion weight loss conforms to the power function model, and its fitting equation is C=0.4273t-0.246. The corrosion products on the surface of the copper tube show a light green dense scale structure, which is well combined with the metal matrix. XPS、EDS and FTIR analysis results show that the main component of the corrosion product is copper green (Cu2 (OH) 2CO3). The electrical test results show that after 16 years of burial, the corrosion rate of the copper tube decreases and the impedance value increases significantly, indicating that the corrosion product film has a good protective effect on the substrate and can effectively slow down the continuous development of the corrosion process.

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李伟光,肖盼,鹿中晖,李英志,夏永生,楚鹰军,潘吉林.紫铜在云南热带雨林土壤中的长期腐蚀行为[J].稀有金属材料与工程,2023,52(11):3915~3921.[Li Weiguang, Xiao Pan, Lu Zhonghui, Li Yingzhi, Xia Yongsheng, Chu Yingjun, Pan Jilin. Long term Corrosion Behavior of Copper in Yunnan Tropical Rainforest Soil[J]. Rare Metal Materials and Engineering,2023,52(11):3915~3921.]
DOI:10.12442/j. issn.1002-185X.20220870

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  • 收稿日期:2022-11-03
  • 最后修改日期:2023-02-06
  • 录用日期:2023-02-14
  • 在线发布日期: 2023-11-27
  • 出版日期: 2023-11-22