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双金属氧化物掺杂对CDPF老化性能的影响
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作者单位:

1.同济大学汽车学院;2.北京市生态环境监测中心

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基金项目:

国家自然科学基金资助(项目号52206167),中央高校基本科研业务费专项资金资助


Effect of bimetal oxide doping on the aging performance of catalyzed DPF
Author:
Affiliation:

1.School of Automotive Studies,Tongji University;2.Beijing Municipal Ecological and Environmental Monitoring Center

Fund Project:

National Natural Science Foundation of China (Project No. 52206167), Fundamental Research Funds for the Central Universities

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    摘要:

    本文基于XRD、XPS、H2-TPR等理化特性表征方法与催化剂活性评价方法,研究了掺杂不同双金属氧化物催化型颗粒捕集器(CDPF)样品水热老化状态下的理化特性与催化活性。结果表明:掺杂Ce-Zr双金属氧化物的CDPF样品物相结构和晶胞参数稳定性较好,掺杂Zr-Fe双金属氧化物的CDPF样品能较好地抑制老化后载体表面贵金属分散度的降低程度。掺杂Fe-Ce和Zr-Fe的CDPF样品在高温老化过程中分散的金属氧化物会再次发生固溶而形成较多的固溶体,带来更多氧空位。经历高温水热老化后,CDPF样品的还原峰均不同程度地向高温方向迁移,其中掺杂Fe-Ce的CDPF样品还原峰迁移幅度较低,掺杂Ce-Zr的CDPF样品还原峰向迁移幅度较大。掺杂Fe-Ce和Zr-Fe的CDPF样品老化后对CO的氧化活性较高,劣化程度较小,并且保持较好的NO催化选择性。掺杂Ce-Zr的CDPF样品老化后对C3H8氧化活性略有下降。

    Abstract:

    Based on XRD, XPS, H2-TPR and other characterization methods for physical and chemical properties and catalyst activity evaluation methods, the physical and chemical properties and catalytic activity of CDPF samples doped with different bimetal oxide under hydrothermal aging condition were studied. The results show that Ce-Zr bimetal oxide doped sample has good stability in phase structure and cell parameters, Zr-Fe bimetal oxide doped sample can better inhibit the dispersity of noble metal on carrier’s surface. For Fe-Ce and Zr-Fe bimetal oxide doped CDPF samples, during high-temperature aging process, the dispersed metal oxides undergo solid solution again, which will cause a formation of solid solution and more oxygen vacancies. After experiencing high-temperature hydrothermal aging process, the diffraction characteristic peaks of samples all migrate various degrees towards the high-temperature direction. Fe-Ce bimetal oxide doped sample shows a low degree of migration while Ce-Zr bimetal oxide doped sample is higher. Fe-Ce and Zr-Fe bimetal oxide doped aged samples showed higher oxidation activity of CO and show a low-level degradation. Ce-Zr bimetal oxide doped aged sample showed a slight decrease in the oxidation activity of C3H8. The catalytic activity for NO of Ce-Zr bimetal oxide doped sample decreases slightly after high-temperature hydrothermal aging process.

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张允华,郑森,楼狄明,房亮,冯谦.双金属氧化物掺杂对CDPF老化性能的影响[J].稀有金属材料与工程,2024,53(5):1391~1400.[Zhang Yunhua, Zheng Sen, Lou Diming, Fang Liang, Feng Qian. Effect of bimetal oxide doping on the aging performance of catalyzed DPF[J]. Rare Metal Materials and Engineering,2024,53(5):1391~1400.]
DOI:10.12442/j. issn.1002-185X.20230334

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  • 收稿日期:2023-05-31
  • 最后修改日期:2023-08-24
  • 录用日期:2023-08-24
  • 在线发布日期: 2024-05-28
  • 出版日期: 2024-05-22