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DD90单晶高温合金热障涂层抗氧化及热循环性能
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中国科学院金属研究所

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中图分类号:

TG174.44

基金项目:

中国科学院金属研究所创新基金(项目号2022-PY08);中国科学院重点部署项目(项目号ZDRW-CN-2021-2-2)


Oxidation resistance and thermal cycling properties of thermal barrier coatings for DD90 single crystal superalloy
Author:
Affiliation:

Institute of Metal Research,Chinese Academy of Sciences

Fund Project:

IMR Innovation Fund (NO. 2022-PY08);Key Research Program of the Chinese Academy of Sciences (NO. ZDRW-CN-2021-2-2)

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    摘要:

    在第三代单晶高温合金DD90上制备热障涂层,采用超音速火焰喷涂(HVOF)制备NiCrAlY+NiCoCrAlTaY双层结构的粘结层,大气等离子喷涂(APS)制备YSZ和MSZ/YSZ结构的陶瓷层。在1150℃抗氧化试验中,YSZ涂层增重量明显高于MSZ涂层。在1200℃热循环250次后,两种涂层没有发生明显相变,MSZ涂层抗烧结性更优异。两种涂层TGO 主要由Al2O3及少量尖晶石结构的混合氧化物组成。双层粘结层减少了Al元素向基材的扩散,而Cr元素由于浓度梯度扩散导致拓扑密堆(TCP)相的析出及二次反应区(SRZ)深度的增加。

    Abstract:

    Thermal barrier coatings were deposited on the third generation single crystal superalloys DD90.NiCrAlY+NiCoCrAlTaY double-layer bond coatings were prepared by high velocity oxy-fuel spray (HVOF).The ceramic layers were YSZ and MSZ/YSZ structures which were prepared by using atmospheric plasma spray technique, respectively. The oxidation resistance test at 1150℃ shows that the weight gain of the YSZ coating is significantly higher than that of the MSZ coating. After 250 thermal cycles at 1200℃, the two coatings do not occur obvious phase transition and the sintering resistance of the MSZ coating is better. The TGO of the two coatings mainly consists of Al2O3 and a small amount of spinel structure mixed oxides. The double-layer bond layer reduces the diffusion of Al element into the substrate, while due to the concentration gradient diffusion of Cr element leads to the precipitation of topological close-packed (TCP) phases and the increase in the depth of secondary reaction zone (SRZ).

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王俊哲,高明浩,徐娜,常辉,崔凤静,栾胜家,贾博文,张甲,常新春. DD90单晶高温合金热障涂层抗氧化及热循环性能[J].稀有金属材料与工程,2023,52(12):4355~4360.[Wang Junzhe, Gao Minghao, Xu Na, Chang Hui, Cui Fengjing, Luan Shengjia, Jia Bowen, Zhang Jia, Chang Xinchun. Oxidation resistance and thermal cycling properties of thermal barrier coatings for DD90 single crystal superalloy[J]. Rare Metal Materials and Engineering,2023,52(12):4355~4360.]
DOI:10.12442/j. issn.1002-185X.20230422

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历史
  • 收稿日期:2023-07-04
  • 最后修改日期:2023-08-22
  • 录用日期:2023-08-24
  • 在线发布日期: 2023-12-29
  • 出版日期: 2023-12-22