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超声表面滚压加工对Zr705合金预腐蚀疲劳行为的影响研究
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西安建筑科技大学

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国家自然科学基金52275161,陕西省重点科技创新团队2023-CX-TD-50,陕西省科技厅-秦创原“科学家+工程师”队伍建设2022KXJ-145


Study on the Effect of Ultrasonic Surface Rolling Process on Pre-corrosion Fatigue behavior of Zr705 Alloy
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Xi’an University of Architecture and Technology,Xi’an

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    摘要:

    本文主要对原始态和超声滚压态Zr705合金分别在1mol/L LiOH溶液、3.5% NaCl溶液、5% HCl溶液中预腐蚀30天后的疲劳性能进行了研究。研究结果表明:原始态Zr705合金在3.5% NaCl溶液中腐蚀程度最严重,在5% HCl溶液中次之,在1mol/L LiOH溶液中腐蚀程度最轻。这与Zr705合金在不同介质中的腐蚀机理不同有关:当Zr705合金处在LiOH溶液中时,主要是O2-和OH-参与腐蚀反应,而Li+并未参与腐蚀反应,而是吸附在氧化膜的孔隙壁和ZrO2的晶界处加速腐蚀;当Zr705合金处在NaCl溶液中时,大量存在的Cl—对腐蚀起主导作用;当Zr705合金处在HCl溶液中时,H+和Cl—都参与了Zr705合金在HCl溶液中的腐蚀过程。USRP-Zr705合金由于表层梯度结构中存在高密度的位错缺陷,较原始态Zr705合金更容易被腐蚀。经浸泡腐蚀处理,原始态Zr705合金疲劳寿命明显下降,这主要是由于试样表面在浸泡腐蚀过程中产生腐蚀损伤导致的。经浸泡腐蚀处理,USRP-Zr705试样在1mol/L LiOH溶液中的疲劳寿命较原始态Zr705合金有所提高,而在3.5% NaCl溶液、5% HCl溶液中疲劳寿命较原始态Zr705合金有所下降。腐蚀环境和表面梯度结构对锆合金疲劳性能的影响存在竞争关系:当腐蚀介质腐蚀性较弱时,表面梯度结构是影响合金疲劳性能的主要因素。当腐蚀介质腐蚀性较强时,在高应力作用下循环加载,表面梯度结构仍是影响合金疲劳性能的主要因素;在低应力作用下循环加载,腐蚀环境是影响合金疲劳性能的主要因素。

    Abstract:

    In this paper, the fatigue properties of Zr705 alloy in original state and ultrasonic rolling state after pre-corrosion in 1mol/L LiOH solution, 3.5% NaCl solution and 5% HCl solution for 30 days were studied. The results show that the corrosion degree of the original Zr705 alloy is the most serious in 3.5% NaCl solution, followed by 5% HCl solution and the least in 1mol/L LiOH solution. This is related to the different corrosion mechanism of Zr705 alloy in different media: when Zr705 alloy is in LiOH solution, mainly O2- and OH- participate in the corrosion reaction, while Li+ does not participate in the corrosion reaction, but is adsorbed on the pore wall of oxide film and the grain boundary of ZrO2 to accelerate the corrosion; When Zr705 alloy is in NaCl solution, a large amount of Cl- plays a leading role in the corrosion reaction. When Zr705 alloy is in HCl solution, both H+ and Cl- participate in the corrosion process of Zr705 alloy in HCl solution. USRP-Zr705 alloy is more easily corroded than the original Zr705 alloy because of the high density dislocation defects in the surface gradient structure. After immersion corrosion treatment, the fatigue life of the original Zr705 alloy decreased obviously, which was mainly caused by corrosion damage on the surface of the sample during immersion corrosion. After immersion corrosion treatment, the fatigue life of USRP-Zr705 sample in 1mol/L LiOH solution is higher than that of the original Zr705 alloy, but it is lower in 3.5% NaCl solution and 5% HCl solution. There is a competitive relationship between the corrosion environment and the surface gradient structure on the fatigue properties of zirconium alloys: when the corrosion medium is weak, the surface gradient structure is the main factor affecting the fatigue properties of zirconium alloys. When the corrosive medium is strong, the surface gradient structure is still the main factor affecting the fatigue properties of the alloy under high stress cyclic loading. Under low stress cyclic loading, corrosion environment is the main factor affecting the fatigue properties of the alloy.

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马驰,张聪惠,朱文光,曾祥康,谢卓航,王浠宇.超声表面滚压加工对Zr705合金预腐蚀疲劳行为的影响研究[J].稀有金属材料与工程,2024,53(10):2831~2842.[MA Chi, ZHANG Conghui, ZHU Wenguang, ZENG Xiangkang, XIE Zhuohang, WANG Xiyu. Study on the Effect of Ultrasonic Surface Rolling Process on Pre-corrosion Fatigue behavior of Zr705 Alloy[J]. Rare Metal Materials and Engineering,2024,53(10):2831~2842.]
DOI:10.12442/j. issn.1002-185X.20230506

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  • 收稿日期:2023-08-16
  • 最后修改日期:2023-10-01
  • 录用日期:2023-10-18
  • 在线发布日期: 2024-10-17
  • 出版日期: 2024-09-27