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Ar/N2-Ar共溅射Ti掺杂对Ta2O5 涂层光学和力学性能的影响
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1.河南科技大学 机电工程学院,河南 洛阳 471003;2.河南省机械设计及传动系统重点实验室,河南 洛阳 471003;3.高端轴承河南省协同创新中心,河南 洛阳 471003;4.莱芜技师学院,山东 莱芜 271100

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Effect of Ar/N2-Ar Co-sputtering Ti Doping on Optical and Mechanical Properties of Ta2O5 Coatings
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1.School of Mechatronics Engineering, Henan University of Science and Technology, Luoyang 471003, China;2.Henan Key Laboratory of Modern Mechanical Design and Transmission System, Luoyang 471003, China;3.Collaborative Innovation Center of Henan Province for High-End Bearing, Luoyang 471003, China;4.Laiwu Technician Institute, Laiwu 271100, China

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National Key R&D Program of China (2021YFB3400401)

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    摘要:

    为了探索Ar/N2-Ar共溅射Ti掺杂对Ta2O5涂层光学性能和力学性能的影响,采用射频和直流磁控共溅射技术在玻璃基底表面制备了Ta2O5、N2-Ta2O5、Ti-Ta2O5和N2-Ti-Ta2O5涂层。利用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、原子力显微镜(AFM)表征了Ta2O5、N2-Ta2O5、Ti-Ta2O5和N2-Ti-Ta2O5涂层的微观结构和表面形貌;通过紫外可见分光光度计测试了涂层的光学参数;采用纳米压痕仪测试了涂层的硬度和杨氏模量。XRD测试结果表明,Ta2O5、N2-Ta2O5、Ti-Ta2O5和N2-Ti-Ta2O5涂层主要以Ta2O5为主体的非晶相结构组成。SEM和AFM结果显示,沉积在玻璃基底上的涂层未出现大面积空隙,溅射粒子在基底表面均匀堆积生长,并且涂层沉积厚度基本一致,厚度误差在5%以内。分别引入N2和Ti及N2-Ti共掺杂,均可降低Ta2O5涂层的粗糙度。光学测试结果表明,分别引入N2和Ti元素,可以提高Ta2O5涂层的平均透射率至81%以上,而N2-Ti共掺杂制备的N2-Ti-Ta2O5涂层平均透射率降低。力学测试结果显示,与Ta2O5涂层对比,N2-Ta2O5和N2-Ti-Ta2O5涂层的硬度显著增大,Ti-Ta2O5涂层硬度基本一致。弹性指数(H/E)和塑性指数(H3/E2)表明,N2-Ta2O5涂层和N2-Ti-Ta2O5涂层具备更好的断裂韧性和抗塑性变形能力。在玻璃表面制备Ta2O5掺杂N2和Ti元素的涂层,可以实现以N2-Ta2O5涂层和N2-Ti-Ta2O5涂层为代表的、同时具备优异光学性能和力学性能的多功能涂层。

    Abstract:

    In order to explore the effects of Ti doping on the optical and mechanical properties of Ta2O5 coatings prepared by Ar/N2-Ar co-sputtering, Ta2O5, N2-Ta2O5, Ti-Ta2O5, and N2-Ti-Ta2O5 coatings were prepared on the glass substrate surface by radio frequency and direct current magnetron co-sputtering techniques. The microstructures and surface morphologies of Ta2O5, N2-Ta2O5, Ti-Ta2O5, and N2-Ti-Ta2O5 coatings were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), and atomic force microscope (AFM). The optical parameters of the coatings were tested by ultraviolet-visible spectrophotometry. The hardness and Young's modulus of the coatings were tested by nanoindentation. XRD test results show that the Ta2O5, N2-Ta2O5, Ti-Ta2O5, and N2-Ti-Ta2O5 coatings mainly consist of amorphous phase structure with Ta2O5 as the main body. SEM and AFM results show that the coatings deposited on the glass substrate do not have extensive voids. The sputtered particles are uniformly piled and grow on the substrate surface. The coating thicknesses are basically the same and the thickness error is within 5%. The separate introduction of N2, Ti, and N2-Ti co-doping can reduce the roughness of Ta2O5 coatings. The optical test results show that the separate introduction of N2 and Ti element can increase the average transmittance of Ta2O5 coatings to more than 81%, whereas the average transmittance of N2-Ti-Ta2O5 coatings prepared by N2-Ti co-doping reduces. Mechanical test results show that compared with that of Ta2O5 coating, the hardness of N2-Ta2O5 and N2-Ti-Ta2O5 coatings increases significantly. The hardness of Ti-Ta2O5 coatings is basically the same. The elasticity index (H/E) and plasticity index (H3/E2) indicate that the N2-Ta2O5 and N2-Ti-Ta2O5 coatings possess better fracture toughness and plastic deformation resistance. The preparation of N2- and Ti-doped Ta2O5 coatings on glass surface can obtain the multifunctional coatings with both excellent optical and mechanical properties, which is represented by N2-Ta2O5 and N2-Ti-Ta2O5 coatings.

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晁瑞,蔡海潮,李航,吕文雪,薛玉君.Ar/N2-Ar共溅射Ti掺杂对Ta2O5 涂层光学和力学性能的影响[J].稀有金属材料与工程,2024,53(6):1574~1581.[Chao Rui, Cai Haichao, Li Hang, Lv Wenxue, Xue Yujun. Effect of Ar/N2-Ar Co-sputtering Ti Doping on Optical and Mechanical Properties of Ta2O5 Coatings[J]. Rare Metal Materials and Engineering,2024,53(6):1574~1581.]
DOI:10.12442/j. issn.1002-185X.20230564

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  • 收稿日期:2023-09-10
  • 最后修改日期:2023-09-19
  • 录用日期:2023-10-07
  • 在线发布日期: 2024-06-20
  • 出版日期: 2024-06-17