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ZrxTiNiCuBe高熵非晶合金的晶化动力学
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中国石油大学(华东)

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ZR2019MEM032


Crystallization Kinetics of ZrxTiNiCuBe High-Entropy Bulk Metallic Glasses
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    摘要:

    利用铜模铸造方法制备了ZrxTiNiCuBe(x=1.5、2、2.5、3、3.5at.%)高熵非晶合金,采用差示扫描量热仪(DSC)对其晶化动力学进行了研究。结果表明,ZrxTiNiCuBe高熵非晶合金的变温晶化为多级晶化过程,与升温速率具有明显动力学效应。利用Kissinger方程计算的变温晶化激活能,均表现为Eg>Ex>Ep1,Ep1

    Abstract:

    High-entropy bulk metallic glasses (HE-BMGs) are novel bulk alloys combined the multi-principal component characteristics of high-entropy alloys with the long-range disordered atomic stacking characteristics of metallic glass. HE-BMGs, like conventional BMGs, are thermodynamically in a metastable state. However, the crystallization processing of HE-BMGs is different from the conventional BMGs. In this paper, non-equiatomic ZrxTiNiCuBe (x=1.5, 2, 2.5, 3, 3.5at.%) HE-BMGs are prepared by copper mold casting method, and their crystallization kinetics was studied by differential scanning calorimeter (DSC) under both non-isochronal and isothermal conditions. The non-isothermal crystallization kinetics of Zrx HE-BMGs showed a multiple-stage processing. The characteristic temperatures increased with the increase of the heating rate, showing obvious kinetics effects. The activation energy calculated by the Kissinger equation showed Eg>Ex>Ep1,indicating that the overcoming the energy barrier for the rearrangement of was more difficult than atoms nucleation process and the grain growth process of crystallization. The activation energy of crystallization event is Ep1

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王彦芳,何雅茹,胡方裕,石志强. ZrxTiNiCuBe高熵非晶合金的晶化动力学[J].稀有金属材料与工程,2024,53(11):3224~3232.[wang yanfang, He Yaru, Hu Fangyu, Shi Zhiqiang. Crystallization Kinetics of ZrxTiNiCuBe High-Entropy Bulk Metallic Glasses[J]. Rare Metal Materials and Engineering,2024,53(11):3224~3232.]
DOI:10.12442/j. issn.1002-185X.20230588

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历史
  • 收稿日期:2023-09-17
  • 最后修改日期:2023-10-16
  • 录用日期:2023-10-18
  • 在线发布日期: 2024-11-20
  • 出版日期: 2024-11-08