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高耐磨GNPs/AlSi10Mg复合材料制备及其耐磨机制研究
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1.福州大学 材料科学与工程学院,福建 福州 350116;2.福建理工大学 材料科学与工程学院,福建 福州 350118;3.福建省祥鑫股份有限公司,福建 福州 350119;4.福建省特种设备检验研究院,福建 福州 350008

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中图分类号:

TB333.1

基金项目:

国家自然科学基金(52271095,51901044,51871057);福建省自然科学基金(2022J01946)


Preparation and Wear-Resistant Mechanism of Highly Wear-Resistant GNPs/AlSi10Mg Composites
Author:
Affiliation:

1.College of Materials Science and Engineering, Fuzhou University, Fuzhou 350116, China;2.School of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350118, China;3.Fujian Xiangxin Co., Ltd, Fuzhou 350119, China;4.Fujian Special Equipment Inspection and Research Institute, Fuzhou 350008, China

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    摘要:

    通过乙基纤维素(EC)对石墨烯纳米片(GNPs)表面改性,结合溶液超声分散和湿法球磨的方法,既实现GNPs和铝基体均匀混合,又抑制GNPs损伤,然后采用放电等离子快速烧结抑制界面反应,制备高耐磨的GNPs/AlSi10Mg复合材料。通过扫描电镜、透射电镜和摩擦试验机等设备对GNPs/AlSi10Mg复合材料的显微组织与耐磨性能进行表征分析,结果表明GNPs适量添加能有效提升复合材料的力学性能,GNPs添加量为0.5wt%时,复合材料的磨损率和摩擦系数最低,分别为7.8×10-4 mm3/(N·m)和0.417,磨损率较基体材料(10.9×10-4 mm3·N-1·m-1)降低了28.4%。GNPs/AlSi10Mg复合材料的磨损机制以磨粒磨损为主,伴随着轻微氧化磨损和粘着磨损。摩擦过程中复合材料试样与对偶接触时,在剪切力作用下GNPs露出表面形成薄膜,可作为润滑剂减少对偶与基体的接触点,防止过多的剥落和分层,起到保护基体的作用。

    Abstract:

    Through the surface modification of graphene nanoparticles (GNPs) by ethyl cellulose (EC), combined with solution ultrasonic dispersion and wet ball milling, GNPs and aluminum matrix were uniformly mixed and GNPs damage was suppressed. Then, highly wear-resistant GNPs/AlSi10Mg composites were prepared by the suppression of interfacial reaction through rapid sintering with discharge plasma. The microstructure and wear-resistant properties of GNPs/AlSi10Mg composites were characterized and analyzed by scanning electron microscope, transmission electron microscope and friction testing machine. The results show that moderate addition of GNPs can effectively improve the mechanical properties of the composites. When the addition amount of GNPs is 0.5wt%, the wear rate and coefficient of friction of the composites are the lowest, which are 7.8×10-4 mm3/(N·m) and 0.417, respectively. The wear rate is reduced by 28.4% compared with that of the matrix material (10.9×10-4 mm3·N-1·m-1). The wear mechanism of GNPs/AlSi10Mg composites is mainly abrasive wear, accompanied by slight oxidative wear and adhesive wear. During the friction process, when the composite specimen is in contact with the dyad, GNPs emerge on the surface to form a thin film under the action of shear force, which can be used as a lubricant to reduce the contact point between the dyad and the matrix, preventing excessive spalling and delamination and thereby protecting the matrix.

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杨燕,韩鑫洋,邱宇潇,林斌,陈俊锋,陈玉龙,陈舒健,邹林池,池海涛,张伟.高耐磨GNPs/AlSi10Mg复合材料制备及其耐磨机制研究[J].稀有金属材料与工程,2025,54(4):952~963.[Yang Yan, Han Xinyang, Qiu Yuxiao, Lin Bin, Chen Junfeng, Chen Yulong, Chen Shujian, Zou Linchi, Chi Haitao, Zhang Wei. Preparation and Wear-Resistant Mechanism of Highly Wear-Resistant GNPs/AlSi10Mg Composites[J]. Rare Metal Materials and Engineering,2025,54(4):952~963.]
DOI:10.12442/j. issn.1002-185X.20230757

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  • 收稿日期:2023-11-24
  • 最后修改日期:2024-01-24
  • 录用日期:2024-01-31
  • 在线发布日期: 2025-04-23
  • 出版日期: 2025-04-21