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陶瓷型芯在热等静压技术中的应用前景与展望
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华中科技大学 材料成形与模具技术国家重点实验室,湖北 武汉 430074

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TQ174.75

基金项目:

安徽省重点研发计划(202104a05020053);国家自然科学基金(U22A202494);中央高校基本科研业务费专项资金(2020kfyXJJS088)


Prospect and Outlook of Ceramic Cores in Hot Isostatic Pressing Process
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State Key Laboratory of Materials Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, China

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    摘要:

    热等静压结合模具控形技术可实现复杂高性能零件近净成形,型芯是控制成形零件内部结构精度的关键。目前型芯主要采用金属材质,但金属型芯存在高温高压变形控形不准、酸腐蚀去除效率低环境不友好、异种元素扩散污染零件、成形粉末易嵌入导致表面质量差等问题,阻碍热等静压向复杂内腔结构零件成形发展。陶瓷型芯材料化学活性低、与金属元素不易互扩散、高温硬度与刚度高不易变形、碱性条件脱芯效率高,有望解决金属型芯引起的上述问题。本文依据铸造用陶瓷型芯领域的代表性文献和研究进展,重点分析了热等静压用陶瓷型芯力学性能和溶失性能间的协同关系。详细介绍和比对了氧化硅基、氧化铝基、氧化钙基、氧化镁基陶瓷用于热等静压型芯的力学性能、溶失性能、抗吸湿性等性能优化思路,以及其复杂高精度结构成形、烧结与后处理方法,并在此基础上展望了陶瓷型芯在热等静压近净成形工艺中的应用难点与发展方向。

    Abstract:

    Hot isostatic pressing combined with mold control technique can achieve near-net shaping of complex high-performance components. The mold core is crucial for controlling the internal structural accuracy of the formed parts. Presently, mold cores predominantly employ metallic materials. However, these metallic cores are susceptible to substantial deformation under elevated temperatures and pressures. The removal of acid-induced corrosion is not only inefficient but also environmentally unsound. The diffusion of foreign elements from the metal mold cores results in contamination of parts. Additionally, issues such as embedding of forming powder into the surface lead to poor surface quality of the parts. These problems hinder the development of hot isostatic pressing to the forming of complex internal cavity parts. Ceramic mold cores exhibit low chemical reactivity and minimal interdiffusion with metal elements. Its high temperature hardness and stiffness confer resistance to deformation, and its core removal rate is high under alkaline conditions. The above advantages offer a potential solution to issues caused by metal cores. Based on representative literature and research advancements in the field of ceramic mold cores for casting, this paper focuses on analyzing the synergistic relationship between the mechanical and dissolution properties of ceramic mold cores used in hot isostatic pressing. This paper provides a detailed introduction and comparison of the optimization strategies for mechanical properties, dissolution performance, and moisture resistance of silicon oxide, aluminum oxide, calcium oxide, and magnesium oxide-based ceramics used in hot isostatic pressing cores. This paper also explores complex high-precision structural formation, sintering, and post-processing methods. Additionally, it anticipates challenges and future directions for the application of ceramic cores in the near-net shaping hot isostatic pressing process.

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卢佳浩,蔡基利,蔡超,史玉升.陶瓷型芯在热等静压技术中的应用前景与展望[J].稀有金属材料与工程,2025,54(4):1072~1086.[Lu Jiahao, Cai Jili, Cai Chao, Shi Yusheng. Prospect and Outlook of Ceramic Cores in Hot Isostatic Pressing Process[J]. Rare Metal Materials and Engineering,2025,54(4):1072~1086.]
DOI:10.12442/j. issn.1002-185X.20230767

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历史
  • 收稿日期:2023-11-28
  • 最后修改日期:2023-12-19
  • 录用日期:2024-01-05
  • 在线发布日期: 2025-04-23
  • 出版日期: 2025-04-21