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粒度对冷压烧结钒酸锶块体电导率的影响研究
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四川大学材料科学与工程学院

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The effect of granularity on the electrical conductivity of cold-pressing sintering strontium vanadate bulks
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    摘要:

    以溶胶凝胶法结合氢还原制备的公斤级微纳米钒酸锶(SrVO3)粉末为原料,采用不同目数筛网(未筛粉、100目、200目和300目)筛分后,通过冷压烧结制备SrVO3块体。研究了SrVO3粉末和块体材料在空气下的热稳定性,探讨了粒度筛分对其原料粒度及分布、块体晶粒尺寸及电导率的影响。结果表明:SrVO3块体在空气中的热稳定性优于SrVO3粉末,发生氧化增重的温度由粉末的335 ℃提高至块体的430 ℃;随着粒度筛分目数的增加,原料粉末的平均粒径降低,粉末电导率增加,对应的冷压烧结块体的电导率也明显提高。粒度筛分可获得粒度更小、更均匀的粉末原料,使冷压烧结制备的块体更致密,为材料中电荷的传导建立更多的有效路径,制备的SrVO3块体电导率达20000 S/cm,比未筛粉制备的块体提高了37%。粒度筛分本质上是原料粒度的优化,进一步细化SrVO3粉末粒度,可望获得更高性能的块体材料,为其在透明导电薄膜、半导体器件、传感器等领域的应用奠定基础。

    Abstract:

    Kilogram-scale micro-nano SrVO3 powder was produced with the sol-gel method combined with hydrogen reduction and heat treatment. Then SrVO3 bulks were prepared by cold pressing and sintering the sifted powders using different mesh sizes (unsifted powder, 100 mesh, 200 mesh, and 300 mesh). The thermal stability of SrVO3 powder and bulks under air was investigated, and the effects of powder granularity sifting on granularity and distribution of their raw material, bulk grain size, and electrical conductivity were also evaluated. The results show that: SrVO3 bulk has better thermal stability in air than SrVO3 powder; the temperature at which oxidative weight increase occurs is enhanced from 335 °C for the powder to 430 °C for the bulk. The mean particle size of the raw material powders decreases, the electrical conductivity of the related cold-pressing sintering bulks is significantly raised, and the conductivity of the powders rises with increasing granularity sifting mesh. Granularity sifting can be used to acquire smaller and more uniform powder raw materials, which will increase the density of the bulks produced by cold-pressing sintering. Furthermore, the material’s more effective routes for the conduction of electric charge are established and the conductivity of the prepared SrVO3 bulk reaches 20,000 S/cm, which is 37% higher than that of the bulk produced by unsifted powder. Granularity sifting is essentially the optimization of the raw material’s particle size. More sifting of the SrVO3 powder’s particle size is expected to yield improved bulk material performance, providing the foundation for its use in transparent conductive films, semiconductor devices, sensors, and other areas.

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陈建波,杨晓娇,杨泞嘉,牛奕博,欧阳林峰,刘颖.粒度对冷压烧结钒酸锶块体电导率的影响研究[J].稀有金属材料与工程,,().[CHEN Jianbo, YANG Xiaojiao, YANG Ningjia, NIU Yibo, OUYANG Linfeng, Ying Liu. The effect of granularity on the electrical conductivity of cold-pressing sintering strontium vanadate bulks[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-03-04
  • 最后修改日期:2024-04-16
  • 录用日期:2024-04-26
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