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Cu、Mo元素合金化对347H不锈钢组织与耐熔盐腐蚀性能影响
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1.兰州理工大学 材料科学与工程学院 省部共建有色金属先进加工与再利用国家重点实验室,甘肃 兰州 730050;2.甘肃酒钢集团宏兴钢铁股份有限公司,甘肃 嘉峪关 735100

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甘肃省重大专项(21ZD3GB001)


Effect of Cu and Mo Alloying on Microstructure and Molten Salt Corrosion Resistance of 347H Stainless Steel
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1.State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China;2.Gansu Jiu Steel Group Hongxing Iron & Steel Co., Ltd, Jiayuguan 735100, China

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Science and Technology Program Project of Gansu Province (21ZD3GB001)

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    摘要:

    对Cu、Mo元素合金化的347H不锈钢在565 ℃的硝酸盐(60% NaNO3+40% KNO3)中进行长达720 h的静态腐蚀实验,通过分析腐蚀产物的物相组成、微观形貌和化学成分,研究Cu、Mo元素对347H不锈钢耐熔盐腐蚀的影响。结果表明:Mo元素可以细化晶粒,使不锈钢具有耐腐蚀性能最好的中等晶粒度;不锈钢在硝酸盐中发生均匀腐蚀,腐蚀层为双层结构,内外层均存在保护基体的腐蚀产物,外层由Fe的氧化物层(Fe2O3、Fe3O4)、NaFeO2层以及少量的MgFe2O4组成,内层主要由尖晶石层(FeCr2O4、MgCr2O4)和Cu2O薄层组成。Cu在内层被氧化形成致密的Cu2O,能有效阻隔O2-等离子向基体渗透。

    Abstract:

    A static corrosion experiment of 347H stainless steel alloyed with elements Cu and Mo was carried out in a nitrate molten salt (60% NaNO3+40% KNO3) at 565 °C for 720 h. The effects of elements Cu and Mo on the corrosion resistance of 347H stainless steel in molten salt were investigated by analyzing the phase composition, microstructure and chemical composition of the corrosion products. The results show that the grain refinement induced by element Mo imparts the stainless steel with optimal corrosion resistance at a medium grain size. Furthermore, the formation of MoC significantly enhances the intergranular corrosion resistance of the stainless steel. The stainless steel exhibits uniform corrosion in the nitrate solution. The corrosion layer displays a dual-layer structure, and the corrosion products protecting matrix are present in both the inner and outer layers. The outer layer consists of a mixture of Fe oxides (Fe2O3, Fe3O4), NaFeO2, and a minor amount of MgFe2O4. Conversely, the inner layer is primarily composed of a spinel layer (FeCr2O4, MgCr2O4) and a thin Cu2O layer. The oxidation of Cu in the inner layer leads to the formation of a dense Cu2O layer, effectively impeding O2- plasma infiltration into the matrix.

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于志琦,赵燕春,刘天增,冯力,马虎文,李具仓,潘吉祥.Cu、Mo元素合金化对347H不锈钢组织与耐熔盐腐蚀性能影响[J].稀有金属材料与工程,2025,54(4):862~870.[Yu Zhiqi, Zhao Yanchun, Liu Tianzeng, Feng Li, Ma Huwen, Li Jucang, Pan Jixiang. Effect of Cu and Mo Alloying on Microstructure and Molten Salt Corrosion Resistance of 347H Stainless Steel[J]. Rare Metal Materials and Engineering,2025,54(4):862~870.]
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  • 收稿日期:2024-03-06
  • 最后修改日期:2024-04-25
  • 录用日期:2024-04-25
  • 在线发布日期: 2025-04-23
  • 出版日期: 2025-04-21