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铍矿变革性冶金(解离纯化)理论及方法
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1.钢铁研究总院有限公司 先进钢铁流程及材料国家重点实验室,北京 100081;2.钢研晟华科技股份有限公司,北京 100081;3.五矿铍业股份有限公司,湖南 衡阳 421513;4.西北稀有金属材料研究院宁夏有限公司,宁夏 石嘴山 753000

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国家重点研发计划National Key Research and Development Program of China (NKRDP): Research on the dissociation and impurity removal mechanism of beryllium ore smelting process (2021YFC2902301);Research on the separation and purification process and equipment of multivariate beryllium solution (2021YFC2902302)


Theory and Method of Transformative Metallurgy (Dissocia-tion and Purification) of Beryllium Ore
Author:
Affiliation:

1.State Key Laboratory for Advanced Iron and Steel Processes and Products, Central Iron and Steel Research Institute Co., Ltd, Beijing 100081, China;2.CISRI Sunward Technology Co., Ltd, Beijing 100081, China;3.China Minmetals Beryllium Co., Ltd, Hengyang 421513, China;4.Northwest Rare Metal Material Research Institute Ningxia Co., Ltd, Shizuishan 753000, China

Fund Project:

National Key Research and Development Program of China (2021YFC2902301, 2021YFC2902302)

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    摘要:

    提出了基于氢氟酸低温解离和利用氟化物溶解度差异性大的特点进行纯化的变革性铍冶金理论和方法,氢氟酸可直接在低温或室温下快速解离铍矿粉,解离率超过99%,AlF3、FeF3、CrF3及MgF2等氟化物溶解度低,再加上同离子效应,无需化学纯化即可制备纯度为99.9%的铍产品。对于4N级以上的高纯铍产品,则可利用铁、铬等氢氧化物沉淀的pH区间明显不同于Be(OH)2沉淀所对应的pH区间的优越特性进行高纯铍的制备。这一方法可用于制备现代铍冶金可制备的大部分铍产品。

    Abstract:

    A transformative beryllium metallurgy theory and method was proposed based on the low-temperature dissociation of hydrofluoric acid and purification by exploiting the large difference of fluoride solubility. Hydrofluoric acid can quickly dissociate beryllium ore powder directly at low or room temperature with more than 99% dissociation rate. The solubility of AlF3, FeF3, CrF3, and MgF2 is low. Coupled with common ion effect, 99.9%-purity beryllium products can be prepared without chemical purification. For high-purity beryllium products of grade 4N or higher, they can be prepared through the superior property that the pH intervals of iron, chromium, and other hydroxide precipitates are distinctly different from those corresponding to Be(OH)2 precipitates. This new method can be used to prepare most of the beryllium products that are prepared by modern beryllium metallurgy.

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郭培民,申耀宗,王磊,孔令兵,王东新,郭庆.铍矿变革性冶金(解离纯化)理论及方法[J].稀有金属材料与工程,2025,54(5):1207~1216.[Guo Peimin, Shen Yaozong, Wang Lei, Kong Lingbing, Wang Dongxin, Guo Qing. Theory and Method of Transformative Metallurgy (Dissocia-tion and Purification) of Beryllium Ore[J]. Rare Metal Materials and Engineering,2025,54(5):1207~1216.]
DOI:10.12442/j. issn.1002-185X.20240130

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  • 收稿日期:2024-03-08
  • 最后修改日期:2024-04-16
  • 录用日期:2024-04-18
  • 在线发布日期: 2025-05-23
  • 出版日期: 2025-05-22