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离心铸造27Cr44Ni5W3Al+MA乙烯裂解炉管原始铸态组织研究
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合肥通用机械研究院有限公司 国家压力容器与管道安全工程技术研究中心 中国石化炉管质量检测检验与评估中心,安徽 合肥 230031

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TG132.3+3

基金项目:

安徽省重点研发计划(202104a05020023);合肥通用机械研究院有限公司青年科技基金(2020011727)


As-cast Microstructure of Centrifugal-Cast 27Cr44Ni5W3Al+MA Ethylene Cracking Furnace Tube
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Affiliation:

National Engineering & Technical Research Center on Pressure Vessels and Piping Safety, Sinopec Inspection and Assessment Center on Furnace Tube, Hefei General Machinery Research Institute Co., Ltd, Hefei 230031, China

Fund Project:

Anhui Provincial Key Research and Development Plan (No.202104a05020023), Youth Science and Technology Fund of Hefei General Machinery Research Institute Co., Ltd. (No.2020011727)

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    摘要:

    为了探明离心铸造27Cr44Ni5W3Al+MA(微合金)乙烯裂解炉管的原始铸态组织,采用XRD、OM、SEM及TEM等对原始铸态炉管进行了相组成分析及显微组织表征。结果表明:炉管原始铸态组织主要为奥氏体基体(γ相)和晶界鱼骨状复相碳化物,其中复相碳化物内部为片层状M7C3,边缘为块状M23C6。此外,还观察到2种形态的Ni3Al(γ′相),分别为在M23C6与基体交界处附近弥散分布的颗粒状及与M23C6相邻的块状。γ相与M23C6及颗粒状γ′相之间均存在立方-立方的位向关系组织中还观察到大量的位错,在远离M23C6的区域分布较为稀疏,在M23C6附近分布较为密集。探讨了离心铸造过程中γ′相和M23C6的析出机理,合金中W元素降低M23C6γ相的错配度,促进M23C6的析出,M23C6γ′相的成分存在互补性,M23C6的析出进一步促进γ′相的析出。

    Abstract:

    To investigate the original as-cast microstructure of 27Cr44Ni5W3Al+MA ethylene cracking furnace tube manufactured by centrifugal casting, the phase composition and microstructure of the as-cast furnace tube were analyzed using XRD, OM, SEM and TEM. The results show that the original as-cast microstructure of the furnace tube is mainly composed of austenite matrix (γ phase) and fishbone-like multi-phase carbides at grain boundaries; the inside of the multi-phase carbides is lamellar M7C3, while the edge is blocky M23C6. In addition, two shapes of Ni3Al (γ′ phase) are observed, namely the granular phase distributed near the junction between M23C6 and matrix, and the blocky phase adjacent to M23C6. Both of M23C6 and granular γ′ have the cube-on-cube orientation relationship with the γ matrix ( , , ; , , . , , ; , , ). In addition, a large number of dislocations are observed in the as-cast microstructure, with sparse distribution away from M23C6 and dense distribution near M23C6. The precipitation mechanism of γ′ and M23C6 during centrifugal casting was also discussed. The W element reduces the lattice misfit between M23C6 and γ phase, thereby promoting the precipitation of M23C6. The chemical composition of M23C6 and γ′ phase exhibit complementarity, and the precipitation of M23C6 further facilitates the formation of γ′ phase.

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吴志刚,陈涛,刘春娇.离心铸造27Cr44Ni5W3Al+MA乙烯裂解炉管原始铸态组织研究[J].稀有金属材料与工程,2025,54(4):937~944.[Wu Zhigang, Chen Tao, Liu Chunjiao. As-cast Microstructure of Centrifugal-Cast 27Cr44Ni5W3Al+MA Ethylene Cracking Furnace Tube[J]. Rare Metal Materials and Engineering,2025,54(4):937~944.]
DOI:10.12442/j. issn.1002-185X.20240136

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  • 收稿日期:2024-03-12
  • 最后修改日期:2024-04-01
  • 录用日期:2024-04-18
  • 在线发布日期: 2025-04-23
  • 出版日期: 2025-04-21