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新型Co-Ni-Al-W高温合金 γ析出相粗化行为及压缩性能
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1.中国机械总院集团 沈阳铸造研究所有限公司,辽宁 沈阳 110022;2.高端装备铸造技术全国重点实验室,辽宁 沈阳 110022

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基金项目:

Natural Science Foundation of Liaoning Province (No. 2023-MSLH-337)


Coarsening Behavior of γ′ Precipitates and Compression Performance of Novel Co-Ni-Al-W Superalloy
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Affiliation:

1.Shenyang Research Institute of Foundry Co., Ltd, China Academy of Machinery, Shenyang 110022, China;2.National Key Laboratory of Advanced Casting Technologies, Shenyang 110022, China

Fund Project:

Natural Science Foundation of Liaoning Province (2023-MSLH-337)

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    摘要:

    研究了一种新型Co-Ni-Al-W高温合金的γ′析出相在多种温度条件下的粗化行为及合金的压缩性能。实验结果表明,合金在时效过程中,γ′相平均半径和体积分数的演化遵循经典的Lifshitz-Slyozov-Wagner模型。γ′相的粗化速率显著依赖于时效温度,具体表现为从800 ℃时的1.30×10-27 m3/s增加到900 ℃时的9.56×10-27 m3/s。γ′相的活化能主要受W元素在γ基体中的扩散影响,其活化能为210 kJ/mol。所制备的Co-Ni-Al-W合金表现出优异的综合性能,特别是具有高γ?相溶解温度(1221 ℃)和低密度(8.7 g/cm3)的良好结合。此外,Co-Ni-Al-W合金在常温和高温下的压缩屈服强度均高于其他γ?强化的Co基高温合金,且该合金在850 ℃下的压缩屈服强度高达774 MPa。

    Abstract:

    The coarsening behavior of γ? precipitate phase at different temperatures and the compressive performance of novel Co-Ni-Al-W superalloy were investigated. Experiment results show that the evolution of the mean radius and volume fraction of the γ? phase obeys the classical Lifshitz-Slyozov-Wagner model. The coarsening rate of the γ? phase exhibits a significant dependence on the aging temperature, which increases from 1.30×10-27 m3/s at 800 °C to 9.56×10-27 m3/s at 900 °C. The activation energy of γ? phase is mainly influenced by the W diffusion in the γ matrix, presenting as 210 kJ/mol. The prepared Co-Ni-Al-W alloy possesses superb comprehensive properties, particularly the good combination of high γ? solvus temperature (1221 °C) and low density (8.7 g/cm3). Besides, the compressive yield strength of the Co-Ni-Al-W alloy at ambient and high temperatures are higher than that of other γ?-strengthened Co-based superalloys. The compressive yield strength of the Co-Ni-Al-W alloy at 850 °C is as high as 774 MPa.

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周成,金磊,荆高扬,于伯岩,赵军.新型Co-Ni-Al-W高温合金 γ析出相粗化行为及压缩性能[J].稀有金属材料与工程,2024,53(10):2786~2793.[Zhou Cheng, Jin Lei, Jing Gaoyang, Yu Boyan, Zhao Jun. Coarsening Behavior of γ′ Precipitates and Compression Performance of Novel Co-Ni-Al-W Superalloy[J]. Rare Metal Materials and Engineering,2024,53(10):2786~2793.]
DOI:10.12442/j. issn.1002-185X.20240244

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  • 收稿日期:2024-04-25
  • 最后修改日期:2024-06-05
  • 录用日期:2024-06-07
  • 在线发布日期: 2024-09-27
  • 出版日期: 2024-09-27