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复合添加SnMnAZ21合金微弧氧化涂层组织和 性能的影响
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作者单位:

1.青岛理工大学 机械与汽车工程学院,山东 青岛 266520;2.青岛理工大学 工业流体节能与污染控制教育部重点实验室,山东 青岛 266520

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中图分类号:

TG174.4;TG146.22

基金项目:

山东省自然科学基金面上项目(ZR2023ME159)


Effect of Sn and Mn Composite Addition on Microstructure and Properties of Micro-arc Oxidation Coating on AZ21 Alloy
Author:
Affiliation:

1.School of Mechanical and Automotive Engineering, Qingdao University of Technology, Qingdao 266520, China;2.Key Lab of Industrial Fluid Energy Conservation and Pollution Control, Ministry of Education,Qingdao University of Technology, Qingdao 266520, China

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    摘要:

    以挤压态Mg-2Al-Zn(AZ21)合金为研究对象,研究了在基体中少量复合添加低成本Sn(1%,质量分数)和Mn(0.5%,质量分数)元素对AZ21合金微弧氧化涂层组织和性能的影响。在基体中复合添加Sn和Mn元素后,并未改变涂层中相的构成,涂层中主要为MgO、MgAl2O4和AlPO4相;涂层厚度和孔隙率稍有增加,厚度由8.49 μm增加到9.60 μm,孔隙率由5.05%增加到5.75%。通过干摩擦磨损实验、浸泡实验和电化学测试分别评估了基体和涂层的耐磨性和耐蚀性。结果表明,微弧氧化涂层明显改善了基体的耐磨性和耐蚀性。Sn和Mn的复合添加改善了涂层的耐磨性,但其涂层的耐蚀性有所下降,涂层的磨损率由3.53×10-5 mm3·(N·m)-1减小到2.993×10-5 mm3·(N·m)-1,涂层的腐蚀电流密度由3.14×10-6 A·cm-2增加 到4.18×10-6 A·cm-2

    Abstract:

    The effects of low-cost Sn (1wt%) and Mn (0.5wt%) composite addition on the microstructure and properties of micro-arc oxidation coatings on extruded Mg-2Al-Zn (AZ21) alloy were studied. After the addition of Sn and Mn elements to the substrate, the phase composition of the coatings remains unchanged, mainly consisting of MgO, MgAl2O4 and AlPO4 phases. The thickness and porosity of the coatings increase slightly, the thickness increases from 8.49 μm to 9.60 μm, and the porosity increases from 5.05% to 5.75%. The wear resistance and corrosion resistance of the substrates and coatings were evaluated by dry friction and wear test, immersion test and potentiodynamic polarization test. The results show that the micro-arc oxidation coating significantly improves the wear resistance and corrosion resistance of the substrate. The composite addition of Sn and Mn improves the wear resistance of the coatings, but their corrosion resistance decreases. The wear rate of the coating decreases from 3.53×10-5 mm3·(N·m)-1 to 2.993×10-5 mm3·(N·m)-1. The corrosion current density of the coating increases from 3.14×10-6 A·cm-2 to 4.18×10-6 A·cm-2.

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高付豪,吕滨江,郭峰,崔宁,徐铁伟.复合添加SnMnAZ21合金微弧氧化涂层组织和 性能的影响[J].稀有金属材料与工程,2025,54(1):171~183.[Gao Fuhao, Lv Binjiang, Guo Feng, Cui Ning, Xu Tiewei. Effect of Sn and Mn Composite Addition on Microstructure and Properties of Micro-arc Oxidation Coating on AZ21 Alloy[J]. Rare Metal Materials and Engineering,2025,54(1):171~183.]
DOI:10.12442/j. issn.1002-185X.20240304

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  • 收稿日期:2024-05-21
  • 最后修改日期:2024-07-15
  • 录用日期:2024-08-06
  • 在线发布日期: 2025-01-24
  • 出版日期: 2025-01-20