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TiZrCuNi钎料真空钎焊TA1接头组织与力学性能
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1.合肥工业大学 材料科学与工程学院,安徽 合肥 230009;2.江苏科技大学 材料科学与工程学院,江苏 镇江 212000;3.哈尔滨焊接研究院有限公司,黑龙江 哈尔滨 150028;4.新乡航空工业(集团)有限公司,河南 新乡 453000;5.郑州机械研究所有限公司,河南 郑州 410100

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TG425

基金项目:

国家重点研发计划(2021YFB3401100);国家自然科学基金(U22A20191)


Microstructure and Mechanical Properties of Vacuum Brazed TA1 Joints with TiZrCuNi Filler Metal
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Affiliation:

1.School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China;2.School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212000, China;3.Harbin Welding Institute Limited Company, Harbin 150028, China;4.AVIC Xinxiang Aviation Industry (Group) Co., Ltd, Xinxiang 453000, China;5.Zhengzhou Research Institute of Mechanical Engineering Co., Ltd, Zhengzhou 410100, China

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    摘要:

    采用Ti-10Zr-10Cu-10Ni粉末钎料分别在钎焊温度为880和910 ℃下、保温30 min的工艺条件下开展了工业纯钛TA1真空钎焊连接试验,并对两组钎焊接头进行了界面组织与性能分析。结果表明,两组焊接接头微观组织均由TA1/针状α-Ti+共析组织(α-Ti+(Ti, Zr)2(Cu, Ni))+残余钎料/TA1构成,Cu、Ni元素主要集中在共析组织与残余钎料中,而Zr元素在针状α-Ti、共析组织以及残余钎料中均存在一定程度的分布。两组焊接接头的力学性能差异较大,880 ℃下的焊接接头的室温拉伸强度约为174 MPa,而910 ℃下的钎焊接头的室温拉伸强度约为491 MPa。维氏硬度方面表现为母材到焊缝中心的硬度逐渐增大,910 ℃下焊缝中心的维氏硬度(HV)约为2842 MPa,而880 ℃下焊缝中心的维氏硬度约为3724 MPa。两种接头的力学差异主要是Zr元素偏聚形成了脆硬的层带状金属间化合物。断口分析结果显示两组接头裂纹均沿着焊缝扩展,880 ℃下的断口表现出解理断裂特征,910 ℃呈现韧性断裂模式。

    Abstract:

    Ti-10Zr-10Cu-10Ni powder was used as a brazing filler for vacuum brazing of commercial pure titanium TA1 at 880 ℃ for 30 min and 910 ℃ for 30 min. Following this, interface microstructure and performance analyses were carried out on two sets of distinct brazed joints. The results show that the microstructure of the two sets of joints is made up of TA1+acicular α-Ti+eutectoid (α-Ti+(Ti, Zr)2(Cu, Ni)+ residual filler/TAl. The Zr elements are scattered in the eutectoid structure, residual filler and acicular α-Ti, while the Cu and Ni elements are mostly distributed in the eutectoid structure and residual filler. The mechanical properties of the two types of brazed joints differ significantly. When exposed to of brazed joint, the tensile strength of brazed joint at room temperature is around 174 MPa. The room temperature tensile strength rises to around 491 MPa when it is subjected to 910 ℃. The hardness of the material exhibits a progressive rise from the base material to the welding center. At 910 ℃, the greatest recorded hardness (HV) is around 2842 MPa, while at 880 °C, the maximum hardness (HV) reaches 3724 MPa. The mechanical difference between the two joints is mostly caused by the separation of Zr element, which create a brittle, layered intermetallic compound. Fracture analysis of the specimens reveals that the cracks in both sets of interfaces propagate along the weld seams. The fracture surface at 880 ℃ exhibits cleavage fracture characteristics, while at 910 ℃ it demonstrates a ductile fracture mode.

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刘大双,李雄辉,许建华,芦笙,方乃文,张玉克,沈元勋,钟素娟,龙伟民.TiZrCuNi钎料真空钎焊TA1接头组织与力学性能[J].稀有金属材料与工程,2025,54(2):394~400.[Liu Dashuang, Li Xionghui, Xu Jianhua, Lu Sheng, Fang Naiwen, Zhang Yuke, Shen Yuanxun, Zhong Sujuan, Long Weiming. Microstructure and Mechanical Properties of Vacuum Brazed TA1 Joints with TiZrCuNi Filler Metal[J]. Rare Metal Materials and Engineering,2025,54(2):394~400.]
DOI:10.12442/j. issn.1002-185X.20240365

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  • 收稿日期:2024-06-19
  • 最后修改日期:2024-10-15
  • 录用日期:2024-10-18
  • 在线发布日期: 2025-02-25
  • 出版日期: 2025-02-20